Heck-type benzylation of olefins with benzyl trifluoroacetates

Hirohisa Narahashi; Akio Yamamoto; Isao Shimizu

doi:10.1246/cl.2004.348

Heck-type benzylation of olefins with benzyl trifluoroacetates

Hirohisa Narahashi, Akio Yamamoto, Isao Shimizu^*

^*Corresponding author for this work

Waseda University

Research output: Contribution to journal › Article › peer-review

51 Citations (Scopus)

Abstract

A new synthetic method for 1-aryl-2-alkenes from 1-olefins by benzylation treating with benzyl trifluoroacetates using palladium-catalyst is developed on the basis of oxidative addition of benzyl carboxylates to Pd(0) complexes to give benzyl(carboxylato)palladium(II) complexes with cleavage of benzyl-oxygen bond.

Original language	English
Pages (from-to)	348-349
Number of pages	2
Journal	Chemistry Letters
Volume	33
Issue number	3
DOIs	https://doi.org/10.1246/cl.2004.348
Publication status	Published - 2004 Mar

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.2004.348

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title = "Heck-type benzylation of olefins with benzyl trifluoroacetates",

abstract = "A new synthetic method for 1-aryl-2-alkenes from 1-olefins by benzylation treating with benzyl trifluoroacetates using palladium-catalyst is developed on the basis of oxidative addition of benzyl carboxylates to Pd(0) complexes to give benzyl(carboxylato)palladium(II) complexes with cleavage of benzyl-oxygen bond.",

author = "Hirohisa Narahashi and Akio Yamamoto and Isao Shimizu",

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AB - A new synthetic method for 1-aryl-2-alkenes from 1-olefins by benzylation treating with benzyl trifluoroacetates using palladium-catalyst is developed on the basis of oxidative addition of benzyl carboxylates to Pd(0) complexes to give benzyl(carboxylato)palladium(II) complexes with cleavage of benzyl-oxygen bond.

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Heck-type benzylation of olefins with benzyl trifluoroacetates

Abstract

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