High-Efficiency Dibromination of Organic Compound in Microfluidic Channel of SI Pillar Array Directly Coated with Iron Catalys

Takuo Sugaya; Daiki Tanaka; Dong Hyun Yoon; Yoshito Nozaki; Tetsushi Sekiguchi; Takashiro Akitsu; Shuichi Shoji

doi:10.1109/TRANSDUCERS.2019.8808687

High-Efficiency Dibromination of Organic Compound in Microfluidic Channel of SI Pillar Array Directly Coated with Iron Catalys

Takuo Sugaya^*, Daiki Tanaka, Dong Hyun Yoon, Yoshito Nozaki, Tetsushi Sekiguchi, Takashiro Akitsu, Shuichi Shoji

^*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

In a microfluidic device developed using a Si micro-pillar array directly coated with an iron catalyst, 4,8-dibromo-1-hydroxy-2-naphthaldehyde was catalytically synthesized with high efficiency. This represents the first dibromination of the organic compound in a microfluidic device. Typical beaker synthesis of the compound takes one day at 50 °C, but the method proposed here was performed at uncontrolled room temperature (23 °C), while reducing the reaction time to about 1 sec.

Original language	English
Title of host publication	2019 20th International Conference on Solid-State Sensors, Actuators and Microsystems and Eurosensors XXXIII, TRANSDUCERS 2019 and EUROSENSORS XXXIII
Publisher	Institute of Electrical and Electronics Engineers Inc.
Pages	2278-2281
Number of pages	4
ISBN (Electronic)	9781728120072
DOIs	https://doi.org/10.1109/TRANSDUCERS.2019.8808687
Publication status	Published - 2019 Jun
Event	20th International Conference on Solid-State Sensors, Actuators and Microsystems and Eurosensors XXXIII, TRANSDUCERS 2019 and EUROSENSORS XXXIII - Berlin, Germany Duration: 2019 Jun 23 → 2019 Jun 27

Publication series

Name	2019 20th International Conference on Solid-State Sensors, Actuators and Microsystems and Eurosensors XXXIII, TRANSDUCERS 2019 and EUROSENSORS XXXIII

Conference

Conference	20th International Conference on Solid-State Sensors, Actuators and Microsystems and Eurosensors XXXIII, TRANSDUCERS 2019 and EUROSENSORS XXXIII
Country/Territory	Germany
City	Berlin
Period	19/6/23 → 19/6/27

Keywords

Dibromination
iron catalyst
microfluidic device
organic compound
pillar array
synthesis method

ASJC Scopus subject areas

Process Chemistry and Technology
Spectroscopy
Electrical and Electronic Engineering
Mechanical Engineering
Electronic, Optical and Magnetic Materials
Control and Optimization
Instrumentation

Access to Document

10.1109/TRANSDUCERS.2019.8808687

Cite this

Sugaya, T., Tanaka, D., Yoon, D. H., Nozaki, Y., Sekiguchi, T., Akitsu, T., & Shoji, S. (2019). High-Efficiency Dibromination of Organic Compound in Microfluidic Channel of SI Pillar Array Directly Coated with Iron Catalys. In 2019 20th International Conference on Solid-State Sensors, Actuators and Microsystems and Eurosensors XXXIII, TRANSDUCERS 2019 and EUROSENSORS XXXIII (pp. 2278-2281). Article 8808687 (2019 20th International Conference on Solid-State Sensors, Actuators and Microsystems and Eurosensors XXXIII, TRANSDUCERS 2019 and EUROSENSORS XXXIII). Institute of Electrical and Electronics Engineers Inc.. https://doi.org/10.1109/TRANSDUCERS.2019.8808687

High-Efficiency Dibromination of Organic Compound in Microfluidic Channel of SI Pillar Array Directly Coated with Iron Catalys. / Sugaya, Takuo; Tanaka, Daiki; Yoon, Dong Hyun et al.
2019 20th International Conference on Solid-State Sensors, Actuators and Microsystems and Eurosensors XXXIII, TRANSDUCERS 2019 and EUROSENSORS XXXIII. Institute of Electrical and Electronics Engineers Inc., 2019. p. 2278-2281 8808687 (2019 20th International Conference on Solid-State Sensors, Actuators and Microsystems and Eurosensors XXXIII, TRANSDUCERS 2019 and EUROSENSORS XXXIII).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Sugaya, T, Tanaka, D, Yoon, DH, Nozaki, Y, Sekiguchi, T, Akitsu, T & Shoji, S 2019, High-Efficiency Dibromination of Organic Compound in Microfluidic Channel of SI Pillar Array Directly Coated with Iron Catalys. in 2019 20th International Conference on Solid-State Sensors, Actuators and Microsystems and Eurosensors XXXIII, TRANSDUCERS 2019 and EUROSENSORS XXXIII., 8808687, 2019 20th International Conference on Solid-State Sensors, Actuators and Microsystems and Eurosensors XXXIII, TRANSDUCERS 2019 and EUROSENSORS XXXIII, Institute of Electrical and Electronics Engineers Inc., pp. 2278-2281, 20th International Conference on Solid-State Sensors, Actuators and Microsystems and Eurosensors XXXIII, TRANSDUCERS 2019 and EUROSENSORS XXXIII, Berlin, Germany, 19/6/23. https://doi.org/10.1109/TRANSDUCERS.2019.8808687

Sugaya T, Tanaka D, Yoon DH, Nozaki Y, Sekiguchi T, Akitsu T et al. High-Efficiency Dibromination of Organic Compound in Microfluidic Channel of SI Pillar Array Directly Coated with Iron Catalys. In 2019 20th International Conference on Solid-State Sensors, Actuators and Microsystems and Eurosensors XXXIII, TRANSDUCERS 2019 and EUROSENSORS XXXIII. Institute of Electrical and Electronics Engineers Inc. 2019. p. 2278-2281. 8808687. (2019 20th International Conference on Solid-State Sensors, Actuators and Microsystems and Eurosensors XXXIII, TRANSDUCERS 2019 and EUROSENSORS XXXIII). doi: 10.1109/TRANSDUCERS.2019.8808687

Sugaya, Takuo ; Tanaka, Daiki ; Yoon, Dong Hyun et al. / High-Efficiency Dibromination of Organic Compound in Microfluidic Channel of SI Pillar Array Directly Coated with Iron Catalys. 2019 20th International Conference on Solid-State Sensors, Actuators and Microsystems and Eurosensors XXXIII, TRANSDUCERS 2019 and EUROSENSORS XXXIII. Institute of Electrical and Electronics Engineers Inc., 2019. pp. 2278-2281 (2019 20th International Conference on Solid-State Sensors, Actuators and Microsystems and Eurosensors XXXIII, TRANSDUCERS 2019 and EUROSENSORS XXXIII).

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abstract = "In a microfluidic device developed using a Si micro-pillar array directly coated with an iron catalyst, 4,8-dibromo-1-hydroxy-2-naphthaldehyde was catalytically synthesized with high efficiency. This represents the first dibromination of the organic compound in a microfluidic device. Typical beaker synthesis of the compound takes one day at 50 °C, but the method proposed here was performed at uncontrolled room temperature (23 °C), while reducing the reaction time to about 1 sec.",

keywords = "Dibromination, iron catalyst, microfluidic device, organic compound, pillar array, synthesis method",

author = "Takuo Sugaya and Daiki Tanaka and Yoon, {Dong Hyun} and Yoshito Nozaki and Tetsushi Sekiguchi and Takashiro Akitsu and Shuichi Shoji",

note = "Funding Information: This work is partly supported by Japan Ministry of Education, Culture, Sports Science & Technology (MEXT) Grant-in-Aid for Scientific Basic Research (A) No. 16H02349 and the Canon Medical Systems Corporation. The authors thank the MEXT Nanotechnology Platform Support Project of Waseda University. Publisher Copyright: {\textcopyright} 2019 IEEE.; 20th International Conference on Solid-State Sensors, Actuators and Microsystems and Eurosensors XXXIII, TRANSDUCERS 2019 and EUROSENSORS XXXIII ; Conference date: 23-06-2019 Through 27-06-2019",

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doi = "10.1109/TRANSDUCERS.2019.8808687",

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AU - Sekiguchi, Tetsushi

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AU - Shoji, Shuichi

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High-Efficiency Dibromination of Organic Compound in Microfluidic Channel of SI Pillar Array Directly Coated with Iron Catalys

Abstract

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Conference

Keywords

ASJC Scopus subject areas

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