High molecular weight aromatic polyformals free of macrocyclic oligomers. A condensative chain polymerization reaction

Kenji Miyatake; Antisar R. Hlil; Allan S. Hay

doi:10.1021/ma002020r

High molecular weight aromatic polyformals free of macrocyclic oligomers. A condensative chain polymerization reaction

Kenji Miyatake, Antisar R. Hlil, Allan S. Hay^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

44 Citations (Scopus)

Abstract

High molecular weight aromatic polyformals free of macrocyclic oligomers were synthesized using condensative chain polymerization reaction. The reaction of bisphenol with methylene bromide in the presence of potassium hydroxide in a solvent like N-methylpyrrolidinone was carried out under high-intensity mixing conditions at about 100° centigrade. The process could be used for the synthesis of corresponding polythioformals from dithiols.

Original language	English
Pages (from-to)	4288-4290
Number of pages	3
Journal	Macromolecules
Volume	34
Issue number	12
DOIs	https://doi.org/10.1021/ma002020r
Publication status	Published - 2001 Jun 5
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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10.1021/ma002020r

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abstract = "High molecular weight aromatic polyformals free of macrocyclic oligomers were synthesized using condensative chain polymerization reaction. The reaction of bisphenol with methylene bromide in the presence of potassium hydroxide in a solvent like N-methylpyrrolidinone was carried out under high-intensity mixing conditions at about 100° centigrade. The process could be used for the synthesis of corresponding polythioformals from dithiols.",

author = "Kenji Miyatake and Hlil, {Antisar R.} and Hay, {Allan S.}",

year = "2001",

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Y1 - 2001/6/5

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AB - High molecular weight aromatic polyformals free of macrocyclic oligomers were synthesized using condensative chain polymerization reaction. The reaction of bisphenol with methylene bromide in the presence of potassium hydroxide in a solvent like N-methylpyrrolidinone was carried out under high-intensity mixing conditions at about 100° centigrade. The process could be used for the synthesis of corresponding polythioformals from dithiols.

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High molecular weight aromatic polyformals free of macrocyclic oligomers. A condensative chain polymerization reaction

Abstract

ASJC Scopus subject areas

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