TY - JOUR
T1 - High-pressure stopped-flow apparatus for the study of fast reactions in solution
AU - Ishihara, Koji
AU - Funahashi, Shigenobu
AU - Tanaka, Motoharu
N1 - Copyright:
Copyright 2007 Elsevier B.V., All rights reserved.
PY - 1982
Y1 - 1982
N2 - A high-pressure stopped-flow apparatus with spectrophotometric detection has been exploited, which enables one to follow fast reactions in various media at pressure up to 2000 kg cm-2. The rate of the following reactions was successfully measured at various pressures: (1) reaction of nickel (II) nitrate with 1-(2-pyridylazo)-2-naphthol in glacial acetic acid and (2) reaction of nickel (II) perchlorate with isoquinoline in N,N-dimethylformamide. The apparatus allows the measurement of activation volumes for reactions with half-lives longer than several milliseconds.
AB - A high-pressure stopped-flow apparatus with spectrophotometric detection has been exploited, which enables one to follow fast reactions in various media at pressure up to 2000 kg cm-2. The rate of the following reactions was successfully measured at various pressures: (1) reaction of nickel (II) nitrate with 1-(2-pyridylazo)-2-naphthol in glacial acetic acid and (2) reaction of nickel (II) perchlorate with isoquinoline in N,N-dimethylformamide. The apparatus allows the measurement of activation volumes for reactions with half-lives longer than several milliseconds.
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U2 - 10.1063/1.1137139
DO - 10.1063/1.1137139
M3 - Article
AN - SCOPUS:0020171567
SN - 0034-6748
VL - 53
SP - 1231
EP - 1234
JO - Review of Scientific Instruments
JF - Review of Scientific Instruments
IS - 8
ER -