Highly enantioselective catalytic isopropenylation of aldehydes using diisopropenylzinc

Takanori Shibata; Kazuhiro Nakatsui; Kenso Soai

doi:10.1016/S0020-1693(99)00300-X

Highly enantioselective catalytic isopropenylation of aldehydes using diisopropenylzinc

Takanori Shibata^*, Kazuhiro Nakatsui, Kenso Soai

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

32 Citations (Scopus)

Abstract

Diisopropenylzinc adds highly enantioselectively to various aldehydes in the presence of a catalytic amount of chiral amino alcohols to give enantiomerically enriched allyl alkanols with up to 92% e.e.

Original language	English
Pages (from-to)	33-36
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	296
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(99)00300-X
Publication status	Published - 1999 Dec 15
Externally published	Yes

Keywords

Alkenyl complexes
Alkylation
Enantioselective catalysis
Zinc complexes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0020-1693(99)00300-X

Cite this

@article{142df56a9cf844558078f0efeff5e414,

title = "Highly enantioselective catalytic isopropenylation of aldehydes using diisopropenylzinc",

abstract = "Diisopropenylzinc adds highly enantioselectively to various aldehydes in the presence of a catalytic amount of chiral amino alcohols to give enantiomerically enriched allyl alkanols with up to 92% e.e.",

keywords = "Alkenyl complexes, Alkylation, Enantioselective catalysis, Zinc complexes",

author = "Takanori Shibata and Kazuhiro Nakatsui and Kenso Soai",

note = "Funding Information: Financial support by a Grant-in-Aid for Scientific Research from the Ministry of Education, Science, Sports and Culture is gratefully acknowledged. We thank Hayami Tabira and Shigeru Yonekubo for experimental assistance.",

year = "1999",

month = dec,

day = "15",

doi = "10.1016/S0020-1693(99)00300-X",

language = "English",

volume = "296",

pages = "33--36",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier BV",

number = "1",

}

TY - JOUR

T1 - Highly enantioselective catalytic isopropenylation of aldehydes using diisopropenylzinc

AU - Shibata, Takanori

AU - Nakatsui, Kazuhiro

AU - Soai, Kenso

N1 - Funding Information: Financial support by a Grant-in-Aid for Scientific Research from the Ministry of Education, Science, Sports and Culture is gratefully acknowledged. We thank Hayami Tabira and Shigeru Yonekubo for experimental assistance.

PY - 1999/12/15

Y1 - 1999/12/15

N2 - Diisopropenylzinc adds highly enantioselectively to various aldehydes in the presence of a catalytic amount of chiral amino alcohols to give enantiomerically enriched allyl alkanols with up to 92% e.e.

AB - Diisopropenylzinc adds highly enantioselectively to various aldehydes in the presence of a catalytic amount of chiral amino alcohols to give enantiomerically enriched allyl alkanols with up to 92% e.e.

KW - Alkenyl complexes

KW - Alkylation

KW - Enantioselective catalysis

KW - Zinc complexes

UR - http://www.scopus.com/inward/record.url?scp=0001993447&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0001993447&partnerID=8YFLogxK

U2 - 10.1016/S0020-1693(99)00300-X

DO - 10.1016/S0020-1693(99)00300-X

M3 - Article

AN - SCOPUS:0001993447

SN - 0020-1693

VL - 296

SP - 33

EP - 36

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1

ER -

Highly enantioselective catalytic isopropenylation of aldehydes using diisopropenylzinc

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this