Highly stable gold(III) complex with a hydantoin ligand in alkaline media

Kenichi Oyaizu; Yutaka Ohtani; Asako Shiozawa; Kenji Sugawara; Takashi Saito; Makoto Yuasa

doi:10.1021/ic050515x

Highly stable gold(III) complex with a hydantoin ligand in alkaline media

Kenichi Oyaizu, Yutaka Ohtani, Asako Shiozawa, Kenji Sugawara, Takashi Saito, Makoto Yuasa^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

32 Citations (Scopus)

Abstract

A novel gold(III) complex with a monodentate 5,5-dimethylhydantoin ligand, [Au(dmh)₄]^-, is square planar in geometry, inert and highly stable in alkaline solutions because of soft acid-base interactions, and electrochemically reduced near -0.3 V vs Ag/AgCl to give a gold(0) film with a high current efficiency.

Original language	English
Pages (from-to)	6915-6917
Number of pages	3
Journal	Inorganic Chemistry
Volume	44
Issue number	20
DOIs	https://doi.org/10.1021/ic050515x
Publication status	Published - 2005 Oct 3
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic050515x

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abstract = "A novel gold(III) complex with a monodentate 5,5-dimethylhydantoin ligand, [Au(dmh)4]-, is square planar in geometry, inert and highly stable in alkaline solutions because of soft acid-base interactions, and electrochemically reduced near -0.3 V vs Ag/AgCl to give a gold(0) film with a high current efficiency.",

author = "Kenichi Oyaizu and Yutaka Ohtani and Asako Shiozawa and Kenji Sugawara and Takashi Saito and Makoto Yuasa",

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AU - Oyaizu, Kenichi

AU - Ohtani, Yutaka

AU - Shiozawa, Asako

AU - Sugawara, Kenji

AU - Saito, Takashi

AU - Yuasa, Makoto

PY - 2005/10/3

Y1 - 2005/10/3

N2 - A novel gold(III) complex with a monodentate 5,5-dimethylhydantoin ligand, [Au(dmh)4]-, is square planar in geometry, inert and highly stable in alkaline solutions because of soft acid-base interactions, and electrochemically reduced near -0.3 V vs Ag/AgCl to give a gold(0) film with a high current efficiency.

AB - A novel gold(III) complex with a monodentate 5,5-dimethylhydantoin ligand, [Au(dmh)4]-, is square planar in geometry, inert and highly stable in alkaline solutions because of soft acid-base interactions, and electrochemically reduced near -0.3 V vs Ag/AgCl to give a gold(0) film with a high current efficiency.

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Highly stable gold(III) complex with a hydantoin ligand in alkaline media

Abstract

ASJC Scopus subject areas

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