Highly stable polyphenylene ionomer membranes from dichlorobiphenyls

Keisuke Shiino; Junpei Miyake; Kenji Miyatake

doi:10.1039/c9cc02475a

Highly stable polyphenylene ionomer membranes from dichlorobiphenyls

Keisuke Shiino, Junpei Miyake, Kenji Miyatake^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

A simple, cost-effective synthetic strategy for highly stable, proton conductive polyphenylene membranes is reported. The title polyphenylene ionomer (SPP-BP) is easily prepared from dichlorobenzenesulfonic acid and dichlorobiphenyls. The SPP-BP membrane with an optimized m-biphenylene/p-biphenylene ratio (i.e., 4: 1) for a hydrophobic moiety exhibits outstanding chemical stability as well as high proton conductivity.

Original language	English
Pages (from-to)	7073-7076
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	49
DOIs	https://doi.org/10.1039/c9cc02475a
Publication status	Published - 2019
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Highly stable polyphenylene ionomer membranes from dichlorobiphenyls",

abstract = "A simple, cost-effective synthetic strategy for highly stable, proton conductive polyphenylene membranes is reported. The title polyphenylene ionomer (SPP-BP) is easily prepared from dichlorobenzenesulfonic acid and dichlorobiphenyls. The SPP-BP membrane with an optimized m-biphenylene/p-biphenylene ratio (i.e., 4: 1) for a hydrophobic moiety exhibits outstanding chemical stability as well as high proton conductivity.",

author = "Keisuke Shiino and Junpei Miyake and Kenji Miyatake",

note = "Funding Information: This work was partly supported by the New Energy and Industrial Technology Development Organization (NEDO) through the SPer-FC Project and by the Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan through a Grant-in-Aid for Scientific Research (KAKENHI JP18K04746, JP18H02030, JP18H05515, and JP18K19111). Publisher Copyright: {\textcopyright} 2019 The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c9cc02475a",

language = "English",

volume = "55",

pages = "7073--7076",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Highly stable polyphenylene ionomer membranes from dichlorobiphenyls

AU - Shiino, Keisuke

AU - Miyake, Junpei

AU - Miyatake, Kenji

N1 - Funding Information: This work was partly supported by the New Energy and Industrial Technology Development Organization (NEDO) through the SPer-FC Project and by the Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan through a Grant-in-Aid for Scientific Research (KAKENHI JP18K04746, JP18H02030, JP18H05515, and JP18K19111). Publisher Copyright: © 2019 The Royal Society of Chemistry.

PY - 2019

Y1 - 2019

N2 - A simple, cost-effective synthetic strategy for highly stable, proton conductive polyphenylene membranes is reported. The title polyphenylene ionomer (SPP-BP) is easily prepared from dichlorobenzenesulfonic acid and dichlorobiphenyls. The SPP-BP membrane with an optimized m-biphenylene/p-biphenylene ratio (i.e., 4: 1) for a hydrophobic moiety exhibits outstanding chemical stability as well as high proton conductivity.

AB - A simple, cost-effective synthetic strategy for highly stable, proton conductive polyphenylene membranes is reported. The title polyphenylene ionomer (SPP-BP) is easily prepared from dichlorobenzenesulfonic acid and dichlorobiphenyls. The SPP-BP membrane with an optimized m-biphenylene/p-biphenylene ratio (i.e., 4: 1) for a hydrophobic moiety exhibits outstanding chemical stability as well as high proton conductivity.

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DO - 10.1039/c9cc02475a

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SP - 7073

EP - 7076

JO - Chemical Communications

JF - Chemical Communications

IS - 49

ER -

Highly stable polyphenylene ionomer membranes from dichlorobiphenyls

Abstract

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