In situ Raman spectroscopy on an operating AA Zn-MnO 2 battery under high discharge currents

Wen Bin Cai; Qingfang Shi; Michael F. Mansuetto; Daniel Alberto Scherson

doi:10.1149/1.1391135

In situ Raman spectroscopy on an operating AA Zn-MnO 2 battery under high discharge currents

Wen Bin Cai, Qingfang Shi, Michael F. Mansuetto, Daniel Alberto Scherson

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

Structural aspects of the passive film on Zn electrodes in an actual Zn/MnO ₂ battery environment have been examined in situ using Raman spectroscopy. These measurements were performed on a modified AA size Energizer battery with one of its ends replaced by an optical window but otherwise using the same components found in commercial devices. Data collected at various stages during high discharge rate (1 A) provided evidence for the presence of crystalline ZnO toward the last stages of discharge with no evidence for Zn(OH) ₂ at any stage during the entire discharge process.

Original language	English
Pages (from-to)	319-320
Number of pages	2
Journal	Electrochemical and Solid-State Letters
Volume	3
Issue number	7
DOIs	https://doi.org/10.1149/1.1391135
Publication status	Published - 2000 Jul 1
Externally published	Yes

ASJC Scopus subject areas

Electrochemistry
Materials Science(all)

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abstract = "Structural aspects of the passive film on Zn electrodes in an actual Zn/MnO 2 battery environment have been examined in situ using Raman spectroscopy. These measurements were performed on a modified AA size Energizer battery with one of its ends replaced by an optical window but otherwise using the same components found in commercial devices. Data collected at various stages during high discharge rate (1 A) provided evidence for the presence of crystalline ZnO toward the last stages of discharge with no evidence for Zn(OH) 2 at any stage during the entire discharge process.",

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AU - Cai, Wen Bin

AU - Shi, Qingfang

AU - Mansuetto, Michael F.

AU - Scherson, Daniel Alberto

PY - 2000/7/1

Y1 - 2000/7/1

N2 - Structural aspects of the passive film on Zn electrodes in an actual Zn/MnO 2 battery environment have been examined in situ using Raman spectroscopy. These measurements were performed on a modified AA size Energizer battery with one of its ends replaced by an optical window but otherwise using the same components found in commercial devices. Data collected at various stages during high discharge rate (1 A) provided evidence for the presence of crystalline ZnO toward the last stages of discharge with no evidence for Zn(OH) 2 at any stage during the entire discharge process.

AB - Structural aspects of the passive film on Zn electrodes in an actual Zn/MnO 2 battery environment have been examined in situ using Raman spectroscopy. These measurements were performed on a modified AA size Energizer battery with one of its ends replaced by an optical window but otherwise using the same components found in commercial devices. Data collected at various stages during high discharge rate (1 A) provided evidence for the presence of crystalline ZnO toward the last stages of discharge with no evidence for Zn(OH) 2 at any stage during the entire discharge process.

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In situ Raman spectroscopy on an operating AA Zn-MnO 2 battery under high discharge currents

Abstract

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