In situ spectroscopy at the quasi-perfect pt(111) single-crystal facet|aqueous electrolyte interface

Iosif Fromondi; Huanfeng Zhu; Daniel Alberto Scherson

doi:10.1021/jp3024414

In situ spectroscopy at the quasi-perfect pt(111) single-crystal facet|aqueous electrolyte interface

Iosif Fromondi, Huanfeng Zhu, Daniel Alberto Scherson^*

^*Corresponding author for this work

Research output: Contribution to journal › Review article › peer-review

8 Citations (Scopus)

Abstract

The area of in situ spectroscopy at quasi-perfect Pt(111) single-crystal facet|aqueous electrolyte interfaces is herein reviewed. Illustrations are provided of the simultaneous application of differential reflectance spectroscopy and second-harmonic generation as static and dynamic probes of ionic and molecular adsorbates. Attention is focused on quantitative studies of bisulfate adsorption as well as of the dynamics of phase transitions and reactivity of carbon monoxide adlayers and their dependence on the applied potential. Also discussed are current limitations of these techniques, as well as possible means to improve their temporal and spatial resolution.

Original language	English
Pages (from-to)	19613-19624
Number of pages	12
Journal	Journal of Physical Chemistry C
Volume	116
Issue number	37
DOIs	https://doi.org/10.1021/jp3024414
Publication status	Published - 2012 Sept 20
Externally published	Yes

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Energy(all)
Physical and Theoretical Chemistry
Surfaces, Coatings and Films

Access to Document

10.1021/jp3024414

Cite this

@article{3b605ddd1fff46c793bf95227d524f27,

title = "In situ spectroscopy at the quasi-perfect pt(111) single-crystal facet|aqueous electrolyte interface",

abstract = "The area of in situ spectroscopy at quasi-perfect Pt(111) single-crystal facet|aqueous electrolyte interfaces is herein reviewed. Illustrations are provided of the simultaneous application of differential reflectance spectroscopy and second-harmonic generation as static and dynamic probes of ionic and molecular adsorbates. Attention is focused on quantitative studies of bisulfate adsorption as well as of the dynamics of phase transitions and reactivity of carbon monoxide adlayers and their dependence on the applied potential. Also discussed are current limitations of these techniques, as well as possible means to improve their temporal and spatial resolution.",

author = "Iosif Fromondi and Huanfeng Zhu and Scherson, {Daniel Alberto}",

year = "2012",

month = sep,

day = "20",

doi = "10.1021/jp3024414",

language = "English",

volume = "116",

pages = "19613--19624",

journal = "Journal of Physical Chemistry C",

issn = "1932-7447",

publisher = "American Chemical Society",

number = "37",

}

TY - JOUR

T1 - In situ spectroscopy at the quasi-perfect pt(111) single-crystal facet|aqueous electrolyte interface

AU - Fromondi, Iosif

AU - Zhu, Huanfeng

AU - Scherson, Daniel Alberto

PY - 2012/9/20

Y1 - 2012/9/20

N2 - The area of in situ spectroscopy at quasi-perfect Pt(111) single-crystal facet|aqueous electrolyte interfaces is herein reviewed. Illustrations are provided of the simultaneous application of differential reflectance spectroscopy and second-harmonic generation as static and dynamic probes of ionic and molecular adsorbates. Attention is focused on quantitative studies of bisulfate adsorption as well as of the dynamics of phase transitions and reactivity of carbon monoxide adlayers and their dependence on the applied potential. Also discussed are current limitations of these techniques, as well as possible means to improve their temporal and spatial resolution.

AB - The area of in situ spectroscopy at quasi-perfect Pt(111) single-crystal facet|aqueous electrolyte interfaces is herein reviewed. Illustrations are provided of the simultaneous application of differential reflectance spectroscopy and second-harmonic generation as static and dynamic probes of ionic and molecular adsorbates. Attention is focused on quantitative studies of bisulfate adsorption as well as of the dynamics of phase transitions and reactivity of carbon monoxide adlayers and their dependence on the applied potential. Also discussed are current limitations of these techniques, as well as possible means to improve their temporal and spatial resolution.

UR - http://www.scopus.com/inward/record.url?scp=84866661274&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84866661274&partnerID=8YFLogxK

U2 - 10.1021/jp3024414

DO - 10.1021/jp3024414

M3 - Review article

AN - SCOPUS:84866661274

SN - 1932-7447

VL - 116

SP - 19613

EP - 19624

JO - Journal of Physical Chemistry C

JF - Journal of Physical Chemistry C

IS - 37

ER -

In situ spectroscopy at the quasi-perfect pt(111) single-crystal facet|aqueous electrolyte interface

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this