Incorporation of tris(2,2′-bipyridine)ruthenium(II) in a synthetic swelling mica with poly(vinylpyrrolidone)

Makoto Ogawa; Masashi Tsujimura; Kazuyuki Kuroda

doi:10.1021/la9915163

Incorporation of tris(2,2′-bipyridine)ruthenium(II) in a synthetic swelling mica with poly(vinylpyrrolidone)

Makoto Ogawa, Masashi Tsujimura, Kazuyuki Kuroda

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

Tris(2,2′-bipyridine)ruthenium(II) ([Ru(bpy)₃]²⁺)-fluortetrasilicic mica-poly(vinylpyrrolidone) intercalation compounds were prepared by the intercalation of poly(vinylpyrrolidone) into the presynthesized [Ru(bpy)₃]²⁺-fluortetrasilicic mica intercalation compounds. The formation of the intercalation compounds was confirmed by the expansion of the interlayer space as well as the spectroscopic observations. Intercalation compounds with variable chemical compositions have been prepared, and the effect of the distribution of the intercalated [Ru(bpy)₃]²⁺ on the luminescence has been discussed. The luminescence probe can be utilized for the study of clay-polymer interactions.

Original language	English
Pages (from-to)	4202-4206
Number of pages	5
Journal	Langmuir
Volume	16
Issue number	9
DOIs	https://doi.org/10.1021/la9915163
Publication status	Published - 2000 May 2
Externally published	Yes

ASJC Scopus subject areas

Materials Science(all)
Condensed Matter Physics
Surfaces and Interfaces
Spectroscopy
Electrochemistry

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abstract = "Tris(2,2′-bipyridine)ruthenium(II) ([Ru(bpy)3]2+)-fluortetrasilicic mica-poly(vinylpyrrolidone) intercalation compounds were prepared by the intercalation of poly(vinylpyrrolidone) into the presynthesized [Ru(bpy)3]2+-fluortetrasilicic mica intercalation compounds. The formation of the intercalation compounds was confirmed by the expansion of the interlayer space as well as the spectroscopic observations. Intercalation compounds with variable chemical compositions have been prepared, and the effect of the distribution of the intercalated [Ru(bpy)3]2+ on the luminescence has been discussed. The luminescence probe can be utilized for the study of clay-polymer interactions.",

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AU - Tsujimura, Masashi

AU - Kuroda, Kazuyuki

PY - 2000/5/2

Y1 - 2000/5/2

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AB - Tris(2,2′-bipyridine)ruthenium(II) ([Ru(bpy)3]2+)-fluortetrasilicic mica-poly(vinylpyrrolidone) intercalation compounds were prepared by the intercalation of poly(vinylpyrrolidone) into the presynthesized [Ru(bpy)3]2+-fluortetrasilicic mica intercalation compounds. The formation of the intercalation compounds was confirmed by the expansion of the interlayer space as well as the spectroscopic observations. Intercalation compounds with variable chemical compositions have been prepared, and the effect of the distribution of the intercalated [Ru(bpy)3]2+ on the luminescence has been discussed. The luminescence probe can be utilized for the study of clay-polymer interactions.

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Incorporation of tris(2,2′-bipyridine)ruthenium(II) in a synthetic swelling mica with poly(vinylpyrrolidone)

Abstract

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