TY - JOUR
T1 - Intercalation of α,ω-Diaminoalkanes in the interlayer space of the protonated form of the layered perovskite H1.8Bi 0.2Sr0.8Ta2O7
AU - Tahara, Seiichi
AU - Yamashita, Takashi
AU - Kajiwara, Go
AU - Sugahara, Yoshiyuki
PY - 2006/11/5
Y1 - 2006/11/5
N2 - α,ω-Diaminoalkanes (NH2(CH2) nNH2; n = 2, 4, 8, and 12) are intercalated in the interlayer space of the protonated form of a layered perovskite, H 1.8Bi0.2Sr0.8Ta2O7 (HSrTa). The amounts of α,ω-diaminoalkanes, which possess a monolayer arrangement in the interlayer space, are calculated as ca. 0.5 per [Bi0.2Sr0.8Ta2O7]. A model for α,ω-diaminoalkane-HSrTa intercalation compounds is proposed, and the model is consistent with that proposed for n-alkylamine-HSrTa intercalation compounds.
AB - α,ω-Diaminoalkanes (NH2(CH2) nNH2; n = 2, 4, 8, and 12) are intercalated in the interlayer space of the protonated form of a layered perovskite, H 1.8Bi0.2Sr0.8Ta2O7 (HSrTa). The amounts of α,ω-diaminoalkanes, which possess a monolayer arrangement in the interlayer space, are calculated as ca. 0.5 per [Bi0.2Sr0.8Ta2O7]. A model for α,ω-diaminoalkane-HSrTa intercalation compounds is proposed, and the model is consistent with that proposed for n-alkylamine-HSrTa intercalation compounds.
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U2 - 10.1246/cl.2006.1292
DO - 10.1246/cl.2006.1292
M3 - Article
AN - SCOPUS:33846664967
SN - 0366-7022
VL - 35
SP - 1292
EP - 1293
JO - Chemistry Letters
JF - Chemistry Letters
IS - 11
ER -