Abstract
Poly(phenylenevinylene) was selected as a linear polymer-type magnetic coupler in polyradicals, because of its developed π-conjugation and solvent-solubility even after substitution on the phenylene ring. An intrachain and through-bond ferromagnetic interaction between the side-chain built-in radical groups was described for the chemically stable poly[4-(3′,5′-di-tert-butylphenoxy)-1,2-phenylenevinylene]. Effects of radical (spin) defects and molecular weight of the polyradical were discussed.
| Original language | English |
|---|---|
| Pages (from-to) | 247-257 |
| Number of pages | 11 |
| Journal | ACS Symposium Series |
| Volume | 644 |
| Publication status | Published - 1996 |
ASJC Scopus subject areas
- Chemistry(all)