Ir(I)-catalyzed intermolecular regio- and enantioselective hydroamination of alkenes with heteroaromatic amines

Shiguang Pan; Kohei Endo; Takanori Shibata

doi:10.1021/ol203318z

Ir(I)-catalyzed intermolecular regio- and enantioselective hydroamination of alkenes with heteroaromatic amines

Shiguang Pan, Kohei Endo, Takanori Shibata^*

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

70 Citations (Scopus)

Abstract

A cationic Ir(I)-C ₃-TUNEPHOS complex catalyzed an intermolecular hydroamination of styrene derivatives with various heteroaromatic amines. The reaction gave Markovnikov products with perfect regioselectivity and good enantioselectivity under solvent-free conditions.

Original language	English
Pages (from-to)	780-783
Number of pages	4
Journal	Organic Letters
Volume	14
Issue number	3
DOIs	https://doi.org/10.1021/ol203318z
Publication status	Published - 2012 Feb 3

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol203318z

Cite this

@article{97f9e30646d1429684dae551d0c95e0a,

title = "Ir(I)-catalyzed intermolecular regio- and enantioselective hydroamination of alkenes with heteroaromatic amines",

abstract = "A cationic Ir(I)-C 3-TUNEPHOS complex catalyzed an intermolecular hydroamination of styrene derivatives with various heteroaromatic amines. The reaction gave Markovnikov products with perfect regioselectivity and good enantioselectivity under solvent-free conditions.",

author = "Shiguang Pan and Kohei Endo and Takanori Shibata",

year = "2012",

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day = "3",

doi = "10.1021/ol203318z",

language = "English",

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journal = "Organic Letters",

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T1 - Ir(I)-catalyzed intermolecular regio- and enantioselective hydroamination of alkenes with heteroaromatic amines

AU - Pan, Shiguang

AU - Endo, Kohei

AU - Shibata, Takanori

PY - 2012/2/3

Y1 - 2012/2/3

N2 - A cationic Ir(I)-C 3-TUNEPHOS complex catalyzed an intermolecular hydroamination of styrene derivatives with various heteroaromatic amines. The reaction gave Markovnikov products with perfect regioselectivity and good enantioselectivity under solvent-free conditions.

AB - A cationic Ir(I)-C 3-TUNEPHOS complex catalyzed an intermolecular hydroamination of styrene derivatives with various heteroaromatic amines. The reaction gave Markovnikov products with perfect regioselectivity and good enantioselectivity under solvent-free conditions.

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U2 - 10.1021/ol203318z

DO - 10.1021/ol203318z

M3 - Article

C2 - 22256899

AN - SCOPUS:84856714192

SN - 1523-7060

VL - 14

SP - 780

EP - 783

JO - Organic Letters

JF - Organic Letters

IS - 3

ER -

Ir(I)-catalyzed intermolecular regio- and enantioselective hydroamination of alkenes with heteroaromatic amines

Abstract

ASJC Scopus subject areas

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