Key factor for the anti-Arrhenius low-temperature heterogeneous catalysis induced by H+ migration: H+ coverage over support

Kota Murakami; Yuta Tanaka; Ryuya Sakai; Yudai Hisai; Sasuga Hayashi; Yuta Mizutani; Takuma Higo; Shuhei Ogo; Jeong Gil Seo; Hideaki Tsuneki; Yasushi Sekine

doi:10.1039/d0cc00482k

Key factor for the anti-Arrhenius low-temperature heterogeneous catalysis induced by H⁺ migration: H⁺ coverage over support

Kota Murakami, Yuta Tanaka, Ryuya Sakai, Yudai Hisai, Sasuga Hayashi, Yuta Mizutani, Takuma Higo, Shuhei Ogo, Jeong Gil Seo, Hideaki Tsuneki, Yasushi Sekine^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

Low-temperature heterogeneous catalytic reaction in an electric field is anticipated as a novel approach for on-demand and small-scale catalytic processes. This report quantitatively reveals the important role of proton coverage on the catalyst support for catalytic ammonia synthesis in an electric field, which shows an anti-Arrhenius behaviour.

Original language	English
Pages (from-to)	3365-3368
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	23
DOIs	https://doi.org/10.1039/d0cc00482k
Publication status	Published - 2020 Mar 21

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/d0cc00482k

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title = "Key factor for the anti-Arrhenius low-temperature heterogeneous catalysis induced by H+ migration: H+ coverage over support",

abstract = "Low-temperature heterogeneous catalytic reaction in an electric field is anticipated as a novel approach for on-demand and small-scale catalytic processes. This report quantitatively reveals the important role of proton coverage on the catalyst support for catalytic ammonia synthesis in an electric field, which shows an anti-Arrhenius behaviour.",

author = "Kota Murakami and Yuta Tanaka and Ryuya Sakai and Yudai Hisai and Sasuga Hayashi and Yuta Mizutani and Takuma Higo and Shuhei Ogo and Seo, {Jeong Gil} and Hideaki Tsuneki and Yasushi Sekine",

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T1 - Key factor for the anti-Arrhenius low-temperature heterogeneous catalysis induced by H+ migration

T2 - H+ coverage over support

AU - Murakami, Kota

AU - Tanaka, Yuta

AU - Sakai, Ryuya

AU - Hisai, Yudai

AU - Hayashi, Sasuga

AU - Mizutani, Yuta

AU - Higo, Takuma

AU - Ogo, Shuhei

AU - Seo, Jeong Gil

AU - Tsuneki, Hideaki

AU - Sekine, Yasushi

PY - 2020/3/21

Y1 - 2020/3/21

N2 - Low-temperature heterogeneous catalytic reaction in an electric field is anticipated as a novel approach for on-demand and small-scale catalytic processes. This report quantitatively reveals the important role of proton coverage on the catalyst support for catalytic ammonia synthesis in an electric field, which shows an anti-Arrhenius behaviour.

AB - Low-temperature heterogeneous catalytic reaction in an electric field is anticipated as a novel approach for on-demand and small-scale catalytic processes. This report quantitatively reveals the important role of proton coverage on the catalyst support for catalytic ammonia synthesis in an electric field, which shows an anti-Arrhenius behaviour.

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JO - Chemical Communications

JF - Chemical Communications

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ER -

Key factor for the anti-Arrhenius low-temperature heterogeneous catalysis induced by H⁺ migration: H⁺ coverage over support

Abstract

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