Layered Silicate-Organic Interncalation Compounds as Photofunctional Materials

Makoto Ogawa; Kazuyuki Kuroda; Chuzo Kato

doi:10.1016/S0167-2991(08)63255-3

Layered Silicate-Organic Interncalation Compounds as Photofunctional Materials

Makoto Ogawa^*, Kazuyuki Kuroda, Chuzo Kato

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The alkylammonium-exchanged swellable layered clay minerals have been prepared and used as immobilizing media for photoactive organic compounds. Anthracene, pyrene and p-aminoazobenzene were incorporated into the interlayer spaces of the long-chain alkylammonium exchanged-smectites. It was revealed from the photoprocesses of the intercalated species that the adsorptive properties of the host materials varied depending on the arrangements of the interlayer alkylammoniumions. Besides the hydrophobic modification by long chain alkylammonium ions. 2-dimensional microporous structure was obtained by pillaring with tetramethylammonium ion.

Original language	English
Pages (from-to)	171-178
Number of pages	8
Journal	Studies in Surface Science and Catalysis
Volume	83
Issue number	C
DOIs	https://doi.org/10.1016/S0167-2991(08)63255-3
Publication status	Published - 1994 Jan 1
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Condensed Matter Physics
Physical and Theoretical Chemistry
Surfaces, Coatings and Films
Materials Chemistry

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10.1016/S0167-2991(08)63255-3

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abstract = "The alkylammonium-exchanged swellable layered clay minerals have been prepared and used as immobilizing media for photoactive organic compounds. Anthracene, pyrene and p-aminoazobenzene were incorporated into the interlayer spaces of the long-chain alkylammonium exchanged-smectites. It was revealed from the photoprocesses of the intercalated species that the adsorptive properties of the host materials varied depending on the arrangements of the interlayer alkylammoniumions. Besides the hydrophobic modification by long chain alkylammonium ions. 2-dimensional microporous structure was obtained by pillaring with tetramethylammonium ion.",

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AU - Ogawa, Makoto

AU - Kuroda, Kazuyuki

AU - Kato, Chuzo

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Y1 - 1994/1/1

N2 - The alkylammonium-exchanged swellable layered clay minerals have been prepared and used as immobilizing media for photoactive organic compounds. Anthracene, pyrene and p-aminoazobenzene were incorporated into the interlayer spaces of the long-chain alkylammonium exchanged-smectites. It was revealed from the photoprocesses of the intercalated species that the adsorptive properties of the host materials varied depending on the arrangements of the interlayer alkylammoniumions. Besides the hydrophobic modification by long chain alkylammonium ions. 2-dimensional microporous structure was obtained by pillaring with tetramethylammonium ion.

AB - The alkylammonium-exchanged swellable layered clay minerals have been prepared and used as immobilizing media for photoactive organic compounds. Anthracene, pyrene and p-aminoazobenzene were incorporated into the interlayer spaces of the long-chain alkylammonium exchanged-smectites. It was revealed from the photoprocesses of the intercalated species that the adsorptive properties of the host materials varied depending on the arrangements of the interlayer alkylammoniumions. Besides the hydrophobic modification by long chain alkylammonium ions. 2-dimensional microporous structure was obtained by pillaring with tetramethylammonium ion.

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JO - Studies in Surface Science and Catalysis

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ER -

Layered Silicate-Organic Interncalation Compounds as Photofunctional Materials

Abstract

ASJC Scopus subject areas

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