Lithium silicon sulfide as an anode material in all-solid-state lithium batteries

Bui Thi Hang; Tsuyoshi Ohnishi; Minoru Osada; Xiaoxiong Xu; Kazunori Takada; Takayoshi Sasaki

doi:10.1016/j.jpowsour.2009.11.136

Lithium silicon sulfide as an anode material in all-solid-state lithium batteries

Bui Thi Hang, Tsuyoshi Ohnishi, Minoru Osada, Xiaoxiong Xu, Kazunori Takada^*, Takayoshi Sasaki

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

The electrochemical properties of Li₂SiS₃ were investigated in a solid electrolyte. Li₂SiS₃ was converted to elemental Si, and the resultant Si was formed into Si-Li alloy in the reduction process; however, the reverse reaction was not completed due to the loss of electronic conduction upon reoxidation. FeS was dispersed as a conductive additive in Li₂SiS₃ films by pulsed laser deposition (PLD). The addition allowed successive reactions to proceed at a large capacity with small capacity-fading during the cycling process in spite of the small FeS fraction. This result indicates that Li₂SiS₃ + FeS thin film is a promising anode for solid-state lithium batteries.

Original language	English
Pages (from-to)	3323-3327
Number of pages	5
Journal	Journal of Power Sources
Volume	195
Issue number	10
DOIs	https://doi.org/10.1016/j.jpowsour.2009.11.136
Publication status	Published - 2010 May 15
Externally published	Yes

Keywords

Anode material
Iron sulfide
Lithium silicon sulfide
Pulsed laser deposition
Solid-state lithium battery

ASJC Scopus subject areas

Electrical and Electronic Engineering
Energy Engineering and Power Technology
Renewable Energy, Sustainability and the Environment
Physical and Theoretical Chemistry

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.jpowsour.2009.11.136

Cite this

@article{6d2d5a0fc02644d9a238e2d2be58c4cd,

title = "Lithium silicon sulfide as an anode material in all-solid-state lithium batteries",

abstract = "The electrochemical properties of Li2SiS3 were investigated in a solid electrolyte. Li2SiS3 was converted to elemental Si, and the resultant Si was formed into Si-Li alloy in the reduction process; however, the reverse reaction was not completed due to the loss of electronic conduction upon reoxidation. FeS was dispersed as a conductive additive in Li2SiS3 films by pulsed laser deposition (PLD). The addition allowed successive reactions to proceed at a large capacity with small capacity-fading during the cycling process in spite of the small FeS fraction. This result indicates that Li2SiS3 + FeS thin film is a promising anode for solid-state lithium batteries.",

keywords = "Anode material, Iron sulfide, Lithium silicon sulfide, Pulsed laser deposition, Solid-state lithium battery",

author = "Hang, {Bui Thi} and Tsuyoshi Ohnishi and Minoru Osada and Xiaoxiong Xu and Kazunori Takada and Takayoshi Sasaki",

year = "2010",

month = may,

day = "15",

doi = "10.1016/j.jpowsour.2009.11.136",

language = "English",

volume = "195",

pages = "3323--3327",

journal = "Journal of Power Sources",

issn = "0378-7753",

publisher = "Elsevier",

number = "10",

}

TY - JOUR

T1 - Lithium silicon sulfide as an anode material in all-solid-state lithium batteries

AU - Hang, Bui Thi

AU - Ohnishi, Tsuyoshi

AU - Osada, Minoru

AU - Xu, Xiaoxiong

AU - Takada, Kazunori

AU - Sasaki, Takayoshi

PY - 2010/5/15

Y1 - 2010/5/15

N2 - The electrochemical properties of Li2SiS3 were investigated in a solid electrolyte. Li2SiS3 was converted to elemental Si, and the resultant Si was formed into Si-Li alloy in the reduction process; however, the reverse reaction was not completed due to the loss of electronic conduction upon reoxidation. FeS was dispersed as a conductive additive in Li2SiS3 films by pulsed laser deposition (PLD). The addition allowed successive reactions to proceed at a large capacity with small capacity-fading during the cycling process in spite of the small FeS fraction. This result indicates that Li2SiS3 + FeS thin film is a promising anode for solid-state lithium batteries.

AB - The electrochemical properties of Li2SiS3 were investigated in a solid electrolyte. Li2SiS3 was converted to elemental Si, and the resultant Si was formed into Si-Li alloy in the reduction process; however, the reverse reaction was not completed due to the loss of electronic conduction upon reoxidation. FeS was dispersed as a conductive additive in Li2SiS3 films by pulsed laser deposition (PLD). The addition allowed successive reactions to proceed at a large capacity with small capacity-fading during the cycling process in spite of the small FeS fraction. This result indicates that Li2SiS3 + FeS thin film is a promising anode for solid-state lithium batteries.

KW - Anode material

KW - Iron sulfide

KW - Lithium silicon sulfide

KW - Pulsed laser deposition

KW - Solid-state lithium battery

UR - http://www.scopus.com/inward/record.url?scp=74149086730&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=74149086730&partnerID=8YFLogxK

U2 - 10.1016/j.jpowsour.2009.11.136

DO - 10.1016/j.jpowsour.2009.11.136

M3 - Article

AN - SCOPUS:74149086730

SN - 0378-7753

VL - 195

SP - 3323

EP - 3327

JO - Journal of Power Sources

JF - Journal of Power Sources

IS - 10

ER -

Lithium silicon sulfide as an anode material in all-solid-state lithium batteries

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this