Living anionic surface initiated polymerization (SIP) of styrene clay surfaces

Q. Zhou; X. Fan; C. Xia; J. Mays; R. Advincula

doi:10.1021/cm0101780

Living anionic surface initiated polymerization (SIP) of styrene clay surfaces

Q. Zhou, X. Fan, C. Xia, J. Mays, R. Advincula^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

110 Citations (Scopus)

Abstract

Anionic surface initiated polymerization (SIP) was investigated to improve the stabilities and grafting densities of polymers on clay. This is a challenge because of the difficulties with the anionic polymerization mechanism and the presence of adventitious H₂O molecules in silicates and clay. Our results showed the living anionic polymerization was only possible with the 1,1-diphenylethylene (DPE) initiator and a reaction protocol involving heating to 120°C. The reaction serves to distinguish between surface and intergallery initiation.

Original language	English
Pages (from-to)	2465-2467
Number of pages	3
Journal	Chemistry of Materials
Volume	13
Issue number	8
DOIs	https://doi.org/10.1021/cm0101780
Publication status	Published - 2001
Externally published	Yes

ASJC Scopus subject areas

Materials Chemistry
Materials Science(all)

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10.1021/cm0101780

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abstract = "Anionic surface initiated polymerization (SIP) was investigated to improve the stabilities and grafting densities of polymers on clay. This is a challenge because of the difficulties with the anionic polymerization mechanism and the presence of adventitious H2O molecules in silicates and clay. Our results showed the living anionic polymerization was only possible with the 1,1-diphenylethylene (DPE) initiator and a reaction protocol involving heating to 120°C. The reaction serves to distinguish between surface and intergallery initiation.",

author = "Q. Zhou and X. Fan and C. Xia and J. Mays and R. Advincula",

year = "2001",

doi = "10.1021/cm0101780",

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T1 - Living anionic surface initiated polymerization (SIP) of styrene clay surfaces

AU - Zhou, Q.

AU - Fan, X.

AU - Xia, C.

AU - Mays, J.

AU - Advincula, R.

PY - 2001

Y1 - 2001

N2 - Anionic surface initiated polymerization (SIP) was investigated to improve the stabilities and grafting densities of polymers on clay. This is a challenge because of the difficulties with the anionic polymerization mechanism and the presence of adventitious H2O molecules in silicates and clay. Our results showed the living anionic polymerization was only possible with the 1,1-diphenylethylene (DPE) initiator and a reaction protocol involving heating to 120°C. The reaction serves to distinguish between surface and intergallery initiation.

AB - Anionic surface initiated polymerization (SIP) was investigated to improve the stabilities and grafting densities of polymers on clay. This is a challenge because of the difficulties with the anionic polymerization mechanism and the presence of adventitious H2O molecules in silicates and clay. Our results showed the living anionic polymerization was only possible with the 1,1-diphenylethylene (DPE) initiator and a reaction protocol involving heating to 120°C. The reaction serves to distinguish between surface and intergallery initiation.

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JF - Chemistry of Materials

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Living anionic surface initiated polymerization (SIP) of styrene clay surfaces

Abstract

ASJC Scopus subject areas

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