Low temperature growth of fully covered single-layer graphene using a CoCu catalyst

Hisashi Sugime*, Lorenzo D'Arsié, Santiago Esconjauregui, Guofang Zhong, Xingyi Wu, Eugen Hildebrandt, Hikmet Sezen, Matteo Amati, Luca Gregoratti, Robert S. Weatherup, John Robertson

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)


A bimetallic CoCu alloy thin-film catalyst is developed that enables the growth of uniform, high-quality graphene at 750 °C in 3 min by chemical vapour deposition. The growth outcome is found to vary significantly as the Cu concentration is varied, with ∼1 at% Cu added to Co yielding complete coverage single-layer graphene growth for the conditions used. The suppression of multilayer formation is attributable to Cu decoration of high reactivity sites on the Co surface which otherwise serve as preferential nucleation sites for multilayer graphene. X-ray photoemission spectroscopy shows that Co and Cu form an alloy at high temperatures, which has a drastically lower carbon solubility, as determined by using the calculated Co-Cu-C ternary phase diagram. Raman spectroscopy confirms the high quality (ID/IG < 0.05) and spatial uniformity of the single-layer graphene. The rational design of a bimetallic catalyst highlights the potential of catalyst alloying for producing two-dimensional materials with tailored properties.

Original languageEnglish
Pages (from-to)14467-14475
Number of pages9
Issue number38
Publication statusPublished - 2017 Oct 14

ASJC Scopus subject areas

  • General Materials Science


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