Low-temperature laser photolysis of benzophenone in neat diethylaniline: Optical detection of an excited triplet state with a strong charge-transfer structure at 77 K

Mikio Hoshino; Hiroshi Seki; Masao Kaneko; Kazuhiko Kinoshita; Haruo Shizuka

doi:10.1016/0009-2614(86)80109-9

Low-temperature laser photolysis of benzophenone in neat diethylaniline: Optical detection of an excited triplet state with a strong charge-transfer structure at 77 K

Mikio Hoshino^*, Hiroshi Seki, Masao Kaneko, Kazuhiko Kinoshita, Haruo Shizuka

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Benzophenone forms a weak complex with diethylaniline in the ground state at 77 K. Laser photolysis studies carried out for a neat diethylaniline solution of benzophenone at 77 K reveal that the excited triplet state of the weak complex has a strong charge-transfer structure and exhibits a transient spectrum composed of the benzophenone anion radical and the cation radical of diethylaniline.

Original language	English
Pages (from-to)	209-212
Number of pages	4
Journal	Chemical Physics Letters
Volume	132
Issue number	2
DOIs	https://doi.org/10.1016/0009-2614(86)80109-9
Publication status	Published - 1986 Dec 5
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Spectroscopy
Condensed Matter Physics
Atomic and Molecular Physics, and Optics
Surfaces and Interfaces

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10.1016/0009-2614(86)80109-9

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abstract = "Benzophenone forms a weak complex with diethylaniline in the ground state at 77 K. Laser photolysis studies carried out for a neat diethylaniline solution of benzophenone at 77 K reveal that the excited triplet state of the weak complex has a strong charge-transfer structure and exhibits a transient spectrum composed of the benzophenone anion radical and the cation radical of diethylaniline.",

author = "Mikio Hoshino and Hiroshi Seki and Masao Kaneko and Kazuhiko Kinoshita and Haruo Shizuka",

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T1 - Low-temperature laser photolysis of benzophenone in neat diethylaniline

T2 - Optical detection of an excited triplet state with a strong charge-transfer structure at 77 K

AU - Hoshino, Mikio

AU - Seki, Hiroshi

AU - Kaneko, Masao

AU - Kinoshita, Kazuhiko

AU - Shizuka, Haruo

PY - 1986/12/5

Y1 - 1986/12/5

N2 - Benzophenone forms a weak complex with diethylaniline in the ground state at 77 K. Laser photolysis studies carried out for a neat diethylaniline solution of benzophenone at 77 K reveal that the excited triplet state of the weak complex has a strong charge-transfer structure and exhibits a transient spectrum composed of the benzophenone anion radical and the cation radical of diethylaniline.

AB - Benzophenone forms a weak complex with diethylaniline in the ground state at 77 K. Laser photolysis studies carried out for a neat diethylaniline solution of benzophenone at 77 K reveal that the excited triplet state of the weak complex has a strong charge-transfer structure and exhibits a transient spectrum composed of the benzophenone anion radical and the cation radical of diethylaniline.

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U2 - 10.1016/0009-2614(86)80109-9

DO - 10.1016/0009-2614(86)80109-9

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ER -

Low-temperature laser photolysis of benzophenone in neat diethylaniline: Optical detection of an excited triplet state with a strong charge-transfer structure at 77 K

Abstract

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