TY - JOUR
T1 - Matrix-isolation infrared and ultraviolet spectroscopic studies of less stable conformers of 1,3,5-hexatriene
AU - Furukawa, Y.
AU - Takeuchi, H.
AU - Harada, I.
AU - Tasumi, M.
N1 - Copyright:
Copyright 2014 Elsevier B.V., All rights reserved.
PY - 1983/7
Y1 - 1983/7
N2 - The infrared spectra of the 3-trans and 3-cis isomers of 1,3,5-hexatriene in low-temperature Ar matrices deposited from a high-temperature nozzle or deposited under irradiation of the Hg 253.7 nm light show a number of new bands. Correspondingly, the ultraviolet spectra of the 3-trans isomer observed under similar experimental conditions show a new absorption at 276 nm. Most of these new infrared bands and the new ultraviolet absorption are attributable to less stable isomers which have the planar s-cis conformation [or gauche conformation(s) close to the planar s-cis] about either one or both of the two CC bonds.
AB - The infrared spectra of the 3-trans and 3-cis isomers of 1,3,5-hexatriene in low-temperature Ar matrices deposited from a high-temperature nozzle or deposited under irradiation of the Hg 253.7 nm light show a number of new bands. Correspondingly, the ultraviolet spectra of the 3-trans isomer observed under similar experimental conditions show a new absorption at 276 nm. Most of these new infrared bands and the new ultraviolet absorption are attributable to less stable isomers which have the planar s-cis conformation [or gauche conformation(s) close to the planar s-cis] about either one or both of the two CC bonds.
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U2 - 10.1016/0022-2860(83)90100-X
DO - 10.1016/0022-2860(83)90100-X
M3 - Article
AN - SCOPUS:0000106050
SN - 0022-2860
VL - 100
SP - 341
EP - 350
JO - Journal of Molecular Structure
JF - Journal of Molecular Structure
IS - C
ER -