Membrane composed of poly(pyridylpropyne-co-trimethylsilylpropyne) and palladiumporphyrin complex and its oxygen quenching performance

Tsuyoshi Hyakutake; Hirotaka Sakaue; Hiroyuki Nishide

Membrane composed of poly(pyridylpropyne-co-trimethylsilylpropyne) and palladiumporphyrin complex and its oxygen quenching performance

Tsuyoshi Hyakutake^*, Hirotaka Sakaue, Hiroyuki Nishide

^*Corresponding author for this work

Waseda Research Institute for Science and Engineering

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

Poly(1-trimethylsilyl-1-propyne-co-3-pyridyl-1-propyne) was prepared as the ligand-polymer of palladiumporphyrin. The copolymer gave a smooth and tough membrane from the solution with palladiumporphyrin. The membrane displayed a strong phosphorescence at 670 nm and was efficiently quenched by oxygen. The Stern-Volmer plots for the membrane yielded a steep slope. The membrane displayed a very high quenching efficiency (oxygen pressure-sensitivity). Aggregation of the porphyrin was suppressed in the membrane by the ligation, to significantly reduce spacial noises in the luminescence measurement or oxygen-pressure sensing.

Original language	English
Title of host publication	Polymer Preprints, Japan
Pages	1466
Number of pages	1
Volume	54
Edition	1
Publication status	Published - 2005
Event	54th SPSJ Annual Meeting 2005 - Yokohama Duration: 2005 May 25 → 2005 May 27

Other

Other	54th SPSJ Annual Meeting 2005
City	Yokohama
Period	05/5/25 → 05/5/27

Keywords

Oxygen sensor
Palladiumporphyrin
Polymer-metal complex
Trimethylsilylpropyne

ASJC Scopus subject areas

Engineering(all)

Cite this

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title = "Membrane composed of poly(pyridylpropyne-co-trimethylsilylpropyne) and palladiumporphyrin complex and its oxygen quenching performance",

abstract = "Poly(1-trimethylsilyl-1-propyne-co-3-pyridyl-1-propyne) was prepared as the ligand-polymer of palladiumporphyrin. The copolymer gave a smooth and tough membrane from the solution with palladiumporphyrin. The membrane displayed a strong phosphorescence at 670 nm and was efficiently quenched by oxygen. The Stern-Volmer plots for the membrane yielded a steep slope. The membrane displayed a very high quenching efficiency (oxygen pressure-sensitivity). Aggregation of the porphyrin was suppressed in the membrane by the ligation, to significantly reduce spacial noises in the luminescence measurement or oxygen-pressure sensing.",

keywords = "Oxygen sensor, Palladiumporphyrin, Polymer-metal complex, Trimethylsilylpropyne",

author = "Tsuyoshi Hyakutake and Hirotaka Sakaue and Hiroyuki Nishide",

year = "2005",

language = "English",

volume = "54",

pages = "1466",

booktitle = "Polymer Preprints, Japan",

edition = "1",

note = "54th SPSJ Annual Meeting 2005 ; Conference date: 25-05-2005 Through 27-05-2005",

}

TY - GEN

T1 - Membrane composed of poly(pyridylpropyne-co-trimethylsilylpropyne) and palladiumporphyrin complex and its oxygen quenching performance

AU - Hyakutake, Tsuyoshi

AU - Sakaue, Hirotaka

AU - Nishide, Hiroyuki

PY - 2005

Y1 - 2005

N2 - Poly(1-trimethylsilyl-1-propyne-co-3-pyridyl-1-propyne) was prepared as the ligand-polymer of palladiumporphyrin. The copolymer gave a smooth and tough membrane from the solution with palladiumporphyrin. The membrane displayed a strong phosphorescence at 670 nm and was efficiently quenched by oxygen. The Stern-Volmer plots for the membrane yielded a steep slope. The membrane displayed a very high quenching efficiency (oxygen pressure-sensitivity). Aggregation of the porphyrin was suppressed in the membrane by the ligation, to significantly reduce spacial noises in the luminescence measurement or oxygen-pressure sensing.

AB - Poly(1-trimethylsilyl-1-propyne-co-3-pyridyl-1-propyne) was prepared as the ligand-polymer of palladiumporphyrin. The copolymer gave a smooth and tough membrane from the solution with palladiumporphyrin. The membrane displayed a strong phosphorescence at 670 nm and was efficiently quenched by oxygen. The Stern-Volmer plots for the membrane yielded a steep slope. The membrane displayed a very high quenching efficiency (oxygen pressure-sensitivity). Aggregation of the porphyrin was suppressed in the membrane by the ligation, to significantly reduce spacial noises in the luminescence measurement or oxygen-pressure sensing.

KW - Oxygen sensor

KW - Palladiumporphyrin

KW - Polymer-metal complex

KW - Trimethylsilylpropyne

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M3 - Conference contribution

AN - SCOPUS:33645648097

VL - 54

SP - 1466

BT - Polymer Preprints, Japan

T2 - 54th SPSJ Annual Meeting 2005

Y2 - 25 May 2005 through 27 May 2005

ER -

Membrane composed of poly(pyridylpropyne-co-trimethylsilylpropyne) and palladiumporphyrin complex and its oxygen quenching performance

Abstract

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Keywords

ASJC Scopus subject areas

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