Molecular structure of a μ-Oxo chromium-iron complex: Rare example of a crystallographically characterized μ-Oxo heterometallic porphyrin

Kenichi Oyaizu*, Agus Haryono, Yukio Nishimura, Kimihisa Yamamoto, Eishun Tsuchida

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)

Abstract

The crystal structure of a μ-oxo heterometallic porphyrin [(pip)(tpp)Cr(III)[OFe(III)[(tpp)] (pip = piperidine) not only confirmed the proposed oxidation state of chromium and iron atoms, but also revealed a unique coordination environment around chromium(III), which is substantially protruded from the porphyrin plane.

Original languageEnglish
Pages (from-to)1781-1784
Number of pages4
JournalBulletin of the Chemical Society of Japan
Volume72
Issue number8
DOIs
Publication statusPublished - 1999 Aug

ASJC Scopus subject areas

  • Chemistry(all)

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