Multicomponent-Reaction-Ready Biomass-Sourced Organic Hybrids Fabricated via the Surface Immobilization of Polymers with Lignin-Based Compounds

Takashi Hamada; Shuhei Yamashita; Masaaki Omichi; Kimio Yoshimura; Yuji Ueki; Noriaki Seko; Ryohei Kakuchi

doi:10.1021/acssuschemeng.8b06812

Multicomponent-Reaction-Ready Biomass-Sourced Organic Hybrids Fabricated via the Surface Immobilization of Polymers with Lignin-Based Compounds

Takashi Hamada^*, Shuhei Yamashita, Masaaki Omichi, Kimio Yoshimura, Yuji Ueki, Noriaki Seko, Ryohei Kakuchi

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Compounds derived from two major biomass components, cellulose and lignin, were artificially recombined via the radiation-induced graft polymerization of vinyl monomers, which could be potentially sourced from lignin, onto cellulose fabric. This process yielded organic hybrids featuring a cellulose substrate and surface aldehyde groups from lignin-obtained vanillin. Then, the surface Kabachnik-Fields three-component reaction (KF-3CR) of poly(methacrylated vanillin) (PMV)-sourced aldehydes was carried out with amines and phosphites. Overall, the surface KF-3CR on the cellulose fabric grafted with PMV represents a facile preparation of multifunctional molecules on cellulose surfaces along with α-amino phosphonate ester integrations.

Original language	English
Pages (from-to)	7795-7803
Number of pages	9
Journal	ACS Sustainable Chemistry and Engineering
Volume	7
Issue number	8
DOIs	https://doi.org/10.1021/acssuschemeng.8b06812
Publication status	Published - 2019 Apr 15
Externally published	Yes

Keywords

Amino phosphonates
Cellulose
Lignin-sourced
Multicomponent reactions
Organic hybrids

ASJC Scopus subject areas

Chemistry(all)
Environmental Chemistry
Chemical Engineering(all)
Renewable Energy, Sustainability and the Environment

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1021/acssuschemeng.8b06812

Cite this

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title = "Multicomponent-Reaction-Ready Biomass-Sourced Organic Hybrids Fabricated via the Surface Immobilization of Polymers with Lignin-Based Compounds",

abstract = "Compounds derived from two major biomass components, cellulose and lignin, were artificially recombined via the radiation-induced graft polymerization of vinyl monomers, which could be potentially sourced from lignin, onto cellulose fabric. This process yielded organic hybrids featuring a cellulose substrate and surface aldehyde groups from lignin-obtained vanillin. Then, the surface Kabachnik-Fields three-component reaction (KF-3CR) of poly(methacrylated vanillin) (PMV)-sourced aldehydes was carried out with amines and phosphites. Overall, the surface KF-3CR on the cellulose fabric grafted with PMV represents a facile preparation of multifunctional molecules on cellulose surfaces along with α-amino phosphonate ester integrations.",

keywords = "Amino phosphonates, Cellulose, Lignin-sourced, Multicomponent reactions, Organic hybrids",

author = "Takashi Hamada and Shuhei Yamashita and Masaaki Omichi and Kimio Yoshimura and Yuji Ueki and Noriaki Seko and Ryohei Kakuchi",

note = "Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",

year = "2019",

month = apr,

day = "15",

doi = "10.1021/acssuschemeng.8b06812",

language = "English",

volume = "7",

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journal = "ACS Sustainable Chemistry and Engineering",

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TY - JOUR

T1 - Multicomponent-Reaction-Ready Biomass-Sourced Organic Hybrids Fabricated via the Surface Immobilization of Polymers with Lignin-Based Compounds

AU - Hamada, Takashi

AU - Yamashita, Shuhei

AU - Omichi, Masaaki

AU - Yoshimura, Kimio

AU - Ueki, Yuji

AU - Seko, Noriaki

AU - Kakuchi, Ryohei

PY - 2019/4/15

Y1 - 2019/4/15

N2 - Compounds derived from two major biomass components, cellulose and lignin, were artificially recombined via the radiation-induced graft polymerization of vinyl monomers, which could be potentially sourced from lignin, onto cellulose fabric. This process yielded organic hybrids featuring a cellulose substrate and surface aldehyde groups from lignin-obtained vanillin. Then, the surface Kabachnik-Fields three-component reaction (KF-3CR) of poly(methacrylated vanillin) (PMV)-sourced aldehydes was carried out with amines and phosphites. Overall, the surface KF-3CR on the cellulose fabric grafted with PMV represents a facile preparation of multifunctional molecules on cellulose surfaces along with α-amino phosphonate ester integrations.

AB - Compounds derived from two major biomass components, cellulose and lignin, were artificially recombined via the radiation-induced graft polymerization of vinyl monomers, which could be potentially sourced from lignin, onto cellulose fabric. This process yielded organic hybrids featuring a cellulose substrate and surface aldehyde groups from lignin-obtained vanillin. Then, the surface Kabachnik-Fields three-component reaction (KF-3CR) of poly(methacrylated vanillin) (PMV)-sourced aldehydes was carried out with amines and phosphites. Overall, the surface KF-3CR on the cellulose fabric grafted with PMV represents a facile preparation of multifunctional molecules on cellulose surfaces along with α-amino phosphonate ester integrations.

KW - Amino phosphonates

KW - Cellulose

KW - Lignin-sourced

KW - Multicomponent reactions

KW - Organic hybrids

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ER -

Multicomponent-Reaction-Ready Biomass-Sourced Organic Hybrids Fabricated via the Surface Immobilization of Polymers with Lignin-Based Compounds

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

Access to Document

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