N-type redox-active benzoylpyridinium-substituted supramolecular gel for an organogel-based rechargeable device

Kan Hatakeyama-Sato; Rieka Ichinoi; Yoshito Sasada; Yusuke Sasaki; Kenichi Oyaizu; Hiroyuki Nishide

doi:10.1246/cl.190085

N-type redox-active benzoylpyridinium-substituted supramolecular gel for an organogel-based rechargeable device

Kan Hatakeyama-Sato, Rieka Ichinoi, Yoshito Sasada, Yusuke Sasaki, Kenichi Oyaizu, Hiroyuki Nishide^*

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

A supramolecular benzoylpyridinium-substituted cyclohexanediamine gelator with n-type redox properties was synthesized. The gelator formed a robust supramolecular network consisting of cyclohexanediamine units. In the organogel, the stable redox reactions of the benzoylpyridinium moieties led to a reversible charge/discharge at 1.05V (vs. Fc/Fc+). A supramolecule- based rechargeable device was fabricated using TEMPO- and benzoylpyridinium-substituted gelators as the cathode and anode, respectively, giving rise to a flexible, transparent, and even self-healable battery.

Original language	English
Pages (from-to)	555-557
Number of pages	3
Journal	Chemistry Letters
Volume	48
Issue number	6
DOIs	https://doi.org/10.1246/cl.190085
Publication status	Published - 2019

Keywords

Charge storage
Redox-active molecule
Supramolecule

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.190085

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@article{6f86d061025145dfaaf753faf782f83e,

title = "N-type redox-active benzoylpyridinium-substituted supramolecular gel for an organogel-based rechargeable device",

abstract = "A supramolecular benzoylpyridinium-substituted cyclohexanediamine gelator with n-type redox properties was synthesized. The gelator formed a robust supramolecular network consisting of cyclohexanediamine units. In the organogel, the stable redox reactions of the benzoylpyridinium moieties led to a reversible charge/discharge at 1.05V (vs. Fc/Fc+). A supramolecule- based rechargeable device was fabricated using TEMPO- and benzoylpyridinium-substituted gelators as the cathode and anode, respectively, giving rise to a flexible, transparent, and even self-healable battery.",

keywords = "Charge storage, Redox-active molecule, Supramolecule",

author = "Kan Hatakeyama-Sato and Rieka Ichinoi and Yoshito Sasada and Yusuke Sasaki and Kenichi Oyaizu and Hiroyuki Nishide",

note = "Funding Information: The work was also partially supported by Grants-in-Aid for Scientific Research (Nos. 17H03072, 18K19120, 18H03921, and 18H05983) from MEXT, Japan. The work was also partially supported by Research Institute for Science and Engineering, Waseda University. K.H.-S. acknowledges financial support from FS research by JXTG Co. Publisher Copyright: {\textcopyright} 2019 The Chemical Society of Japan.",

year = "2019",

doi = "10.1246/cl.190085",

language = "English",

volume = "48",

pages = "555--557",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Chemical Society of Japan",

number = "6",

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TY - JOUR

T1 - N-type redox-active benzoylpyridinium-substituted supramolecular gel for an organogel-based rechargeable device

AU - Hatakeyama-Sato, Kan

AU - Ichinoi, Rieka

AU - Sasada, Yoshito

AU - Sasaki, Yusuke

AU - Oyaizu, Kenichi

AU - Nishide, Hiroyuki

N1 - Funding Information: The work was also partially supported by Grants-in-Aid for Scientific Research (Nos. 17H03072, 18K19120, 18H03921, and 18H05983) from MEXT, Japan. The work was also partially supported by Research Institute for Science and Engineering, Waseda University. K.H.-S. acknowledges financial support from FS research by JXTG Co. Publisher Copyright: © 2019 The Chemical Society of Japan.

PY - 2019

Y1 - 2019

N2 - A supramolecular benzoylpyridinium-substituted cyclohexanediamine gelator with n-type redox properties was synthesized. The gelator formed a robust supramolecular network consisting of cyclohexanediamine units. In the organogel, the stable redox reactions of the benzoylpyridinium moieties led to a reversible charge/discharge at 1.05V (vs. Fc/Fc+). A supramolecule- based rechargeable device was fabricated using TEMPO- and benzoylpyridinium-substituted gelators as the cathode and anode, respectively, giving rise to a flexible, transparent, and even self-healable battery.

AB - A supramolecular benzoylpyridinium-substituted cyclohexanediamine gelator with n-type redox properties was synthesized. The gelator formed a robust supramolecular network consisting of cyclohexanediamine units. In the organogel, the stable redox reactions of the benzoylpyridinium moieties led to a reversible charge/discharge at 1.05V (vs. Fc/Fc+). A supramolecule- based rechargeable device was fabricated using TEMPO- and benzoylpyridinium-substituted gelators as the cathode and anode, respectively, giving rise to a flexible, transparent, and even self-healable battery.

KW - Charge storage

KW - Redox-active molecule

KW - Supramolecule

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UR - http://www.scopus.com/inward/citedby.url?scp=85066815082&partnerID=8YFLogxK

U2 - 10.1246/cl.190085

DO - 10.1246/cl.190085

M3 - Article

AN - SCOPUS:85066815082

SN - 0366-7022

VL - 48

SP - 555

EP - 557

JO - Chemistry Letters

JF - Chemistry Letters

IS - 6

ER -

N-type redox-active benzoylpyridinium-substituted supramolecular gel for an organogel-based rechargeable device

Abstract

Keywords

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