On the shape of the cyclic voltammetry peaks of species irreversibly adsorbed on electrode surfaces

H. Gerischer; Daniel Alberto Scherson

doi:10.1016/S0022-0728(85)80047-4

On the shape of the cyclic voltammetry peaks of species irreversibly adsorbed on electrode surfaces

H. Gerischer^*, Daniel Alberto Scherson

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

A theory has been developed which accounts for certain deviations from the ideal cyclic voltammetric behavior of molecules adsorbed irreversibly on electrode surfaces. This new model considers explicitly the interactions of the electric field at the interface with the permanent dipole moment of the adsorbed species. Good quantitative agreement has been obtained with experimental data reported earlier in the literature.

Original language	English
Pages (from-to)	33-38
Number of pages	6
Journal	Journal of Electroanalytical Chemistry
Volume	188
Issue number	1-2
DOIs	https://doi.org/10.1016/S0022-0728(85)80047-4
Publication status	Published - 1985 Jun 25
Externally published	Yes

ASJC Scopus subject areas

Analytical Chemistry
Chemical Engineering(all)
Electrochemistry

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10.1016/S0022-0728(85)80047-4

Cite this

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abstract = "A theory has been developed which accounts for certain deviations from the ideal cyclic voltammetric behavior of molecules adsorbed irreversibly on electrode surfaces. This new model considers explicitly the interactions of the electric field at the interface with the permanent dipole moment of the adsorbed species. Good quantitative agreement has been obtained with experimental data reported earlier in the literature.",

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AU - Scherson, Daniel Alberto

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AB - A theory has been developed which accounts for certain deviations from the ideal cyclic voltammetric behavior of molecules adsorbed irreversibly on electrode surfaces. This new model considers explicitly the interactions of the electric field at the interface with the permanent dipole moment of the adsorbed species. Good quantitative agreement has been obtained with experimental data reported earlier in the literature.

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ER -

On the shape of the cyclic voltammetry peaks of species irreversibly adsorbed on electrode surfaces

Abstract

ASJC Scopus subject areas

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