Oxygen-permselectivity in new type polyorganosiloxanes with carboxyl group on the side chain

Manshi Ohyanagi; Hiroyuki Nishide; Koichi Suenaga; Eishun Tsuchida

doi:10.1007/BF01033110

Oxygen-permselectivity in new type polyorganosiloxanes with carboxyl group on the side chain

Manshi Ohyanagi^*, Hiroyuki Nishide, Koichi Suenaga, Eishun Tsuchida

^*Corresponding author for this work

Waseda Research Institute for Science and Engineering

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

Oxygen-permselectivity through polyorganosiloxanes with carboxyl group on the side chain is discussed in terms of the differences between the O₂, N₂ diffusion coefficients or their solubility coefficients. The oxygen-selectivity increases from 2 to 5 with the increase in the carboxyl component of the side chain. Especially the selectivity in the diffusion coefficient is found to more contribute to the oxygenpermselectivity in comparison with that of the solubility coefficient. But the permeation coefficient decreases with the permselectivity.

Original language	English
Pages (from-to)	637-642
Number of pages	6
Journal	Polymer Bulletin
Volume	23
Issue number	6
DOIs	https://doi.org/10.1007/BF01033110
Publication status	Published - 1990 Jun

ASJC Scopus subject areas

Polymers and Plastics
Materials Chemistry

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10.1007/BF01033110

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abstract = "Oxygen-permselectivity through polyorganosiloxanes with carboxyl group on the side chain is discussed in terms of the differences between the O2, N2 diffusion coefficients or their solubility coefficients. The oxygen-selectivity increases from 2 to 5 with the increase in the carboxyl component of the side chain. Especially the selectivity in the diffusion coefficient is found to more contribute to the oxygenpermselectivity in comparison with that of the solubility coefficient. But the permeation coefficient decreases with the permselectivity.",

author = "Manshi Ohyanagi and Hiroyuki Nishide and Koichi Suenaga and Eishun Tsuchida",

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T1 - Oxygen-permselectivity in new type polyorganosiloxanes with carboxyl group on the side chain

AU - Ohyanagi, Manshi

AU - Nishide, Hiroyuki

AU - Suenaga, Koichi

AU - Tsuchida, Eishun

PY - 1990/6

Y1 - 1990/6

N2 - Oxygen-permselectivity through polyorganosiloxanes with carboxyl group on the side chain is discussed in terms of the differences between the O2, N2 diffusion coefficients or their solubility coefficients. The oxygen-selectivity increases from 2 to 5 with the increase in the carboxyl component of the side chain. Especially the selectivity in the diffusion coefficient is found to more contribute to the oxygenpermselectivity in comparison with that of the solubility coefficient. But the permeation coefficient decreases with the permselectivity.

AB - Oxygen-permselectivity through polyorganosiloxanes with carboxyl group on the side chain is discussed in terms of the differences between the O2, N2 diffusion coefficients or their solubility coefficients. The oxygen-selectivity increases from 2 to 5 with the increase in the carboxyl component of the side chain. Especially the selectivity in the diffusion coefficient is found to more contribute to the oxygenpermselectivity in comparison with that of the solubility coefficient. But the permeation coefficient decreases with the permselectivity.

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Oxygen-permselectivity in new type polyorganosiloxanes with carboxyl group on the side chain

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ASJC Scopus subject areas

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