Oxygenation of a new bis-fenced porphyrinato iron without amide groups: 5,10,15,20-Tetrakis(2,6-bispivaloyloxyphenyl)porphyrinatoiron(II)

Teruyuki Komatsu, Etsuo Hasegawa, Hiroyuki Nishide, Eishun Tsuchida*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

A new porphyrinatoiron complex, 5,10,15,20-tetrakis(2,6- bispivaloyloxyphenyl)porphyrinatoriron(II), has been synthesized; axial-base ligation was sterically depressed by the four ester groups on each side of the porphyrin plane and a stable dioxygen adduct formed reversibly at 25°C in toluene.

Original languageEnglish
Pages (from-to)66-68
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number1
DOIs
Publication statusPublished - 1990

ASJC Scopus subject areas

  • Molecular Medicine

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