[PE1-019] Effect of FeO                         
                        x
                                                  on the liquidus line of the Al                         
                        2
                                                 O                         
                        3
                                                 -CaO-SiO                         
                        2
                                                 -Cr                         
                        2
                                                 O                          
                        3
                                                  system at 1573K

Daiki Fujiwara; Hidehiro Sekimoto; Katsunori Yamaguchi

[PE1-019] Effect of FeO _x on the liquidus line of the Al ₂ O ₃ -CaO-SiO ₂ -Cr ₂ O ₃ system at 1573K

Daiki Fujiwara, Hidehiro Sekimoto, Katsunori Yamaguchi

School of Creative Science and Engineering

Research output: Contribution to conference › Paper › peer-review

Abstract

The shredder dust such as an automobile and a home electric appliance is treated in the copper smelting to recover the copper and precious metals in the dust. These secondary materials include combustibles components and chlorine with valuable metals. These are incinerated in rotary kiln furnace to remove combustion and the chlorine of the combustibles component. These are incinerated in rotary kiln furnace to remove combustion and the chlorine of the combustibles component. Refractory including Al ₂ O ₃ or Cr ₂ O ₃ is used in the rotary kiln furnace and has strong heat resistance. However, an erosion of the refractory of Al ₂ O ₃ was sometimes observed with the FeO _x -CaO-SiO ₂ slag. When we consider prolongation of human life of a furnace, A knowledge about the reaction of Al ₂ O ₃ and the FeO _x content slag is important. To characterize the phase equilibria relevant to the slags experimental studies have been carried out to determine liquidus lines of the FeO _x -CaO-SiO ₂ -Al ₂ O ₃ -Cr ₂ O ₃ system with some fixed CaO/SiO ₂ mass% ratios and 3.0mass% Cr ₂ O ₃ at 1573 K. It was found that the influence of the addition of Cr ₂ O ₃ is small to slag liquidus of Al ₂ O ₃ -CaO-SiO ₂ ternary system. In the measurement range from 0 to 15mass% FeO _x , the liquidus line of anorthite primary phase field in the the FeO _x -CaO-SiO ₂ -Al ₂ O ₃ -Cr ₂ O ₃ system does not change with the CaO/SiO ₂ ratios of 0.3 to 0.6. On the other hand, the liquid phase was expanded with an increase of the FeO _x content except for 0.3 <mass%CaO/mass%SiO2 ratios <0.6.

Original language	English
Publication status	Published - 2017 Jan 1
Event	14th International Symposium on East Asian Resources Recycling Technology, EARTH 2017 - Sapporo, Hokkaido, Japan Duration: 2017 Sept 26 → 2017 Sept 29

Conference

Conference	14th International Symposium on East Asian Resources Recycling Technology, EARTH 2017
Country/Territory	Japan
City	Sapporo, Hokkaido
Period	17/9/26 → 17/9/29

Keywords

Alumina refractory
Anorthite
Erosion
Phase diagram

ASJC Scopus subject areas

General Environmental Science

Cite this

Fujiwara, D., Sekimoto, H., & Yamaguchi, K. (2017). [PE1-019] Effect of FeO _x on the liquidus line of the Al ₂ O ₃ -CaO-SiO ₂ -Cr ₂ O ₃ system at 1573K . Paper presented at 14th International Symposium on East Asian Resources Recycling Technology, EARTH 2017, Sapporo, Hokkaido, Japan.

[PE1-019] Effect of FeO _x on the liquidus line of the Al ₂ O ₃ -CaO-SiO ₂ -Cr ₂ O ₃ system at 1573K . / Fujiwara, Daiki; Sekimoto, Hidehiro; Yamaguchi, Katsunori.
2017. Paper presented at 14th International Symposium on East Asian Resources Recycling Technology, EARTH 2017, Sapporo, Hokkaido, Japan.

Research output: Contribution to conference › Paper › peer-review

Fujiwara, D, Sekimoto, H & Yamaguchi, K 2017, ' [PE1-019] Effect of FeO _x on the liquidus line of the Al ₂ O ₃ -CaO-SiO ₂ -Cr ₂ O ₃ system at 1573K ', Paper presented at 14th International Symposium on East Asian Resources Recycling Technology, EARTH 2017, Sapporo, Hokkaido, Japan, 17/9/26 - 17/9/29.

Fujiwara D, Sekimoto H, Yamaguchi K. [PE1-019] Effect of FeO _x on the liquidus line of the Al ₂ O ₃ -CaO-SiO ₂ -Cr ₂ O ₃ system at 1573K . 2017. Paper presented at 14th International Symposium on East Asian Resources Recycling Technology, EARTH 2017, Sapporo, Hokkaido, Japan.

Fujiwara, Daiki ; Sekimoto, Hidehiro ; Yamaguchi, Katsunori. / [PE1-019] Effect of FeO _x on the liquidus line of the Al ₂ O ₃ -CaO-SiO ₂ -Cr ₂ O ₃ system at 1573K Paper presented at 14th International Symposium on East Asian Resources Recycling Technology, EARTH 2017, Sapporo, Hokkaido, Japan.

@conference{c03c95af10a24c2fae9d85bcde6609fc,

title = " [PE1-019] Effect of FeO x on the liquidus line of the Al 2 O 3 -CaO-SiO 2 -Cr 2 O 3 system at 1573K ",

abstract = " The shredder dust such as an automobile and a home electric appliance is treated in the copper smelting to recover the copper and precious metals in the dust. These secondary materials include combustibles components and chlorine with valuable metals. These are incinerated in rotary kiln furnace to remove combustion and the chlorine of the combustibles component. These are incinerated in rotary kiln furnace to remove combustion and the chlorine of the combustibles component. Refractory including Al 2 O 3 or Cr 2 O 3 is used in the rotary kiln furnace and has strong heat resistance. However, an erosion of the refractory of Al 2 O 3 was sometimes observed with the FeO x -CaO-SiO 2 slag. When we consider prolongation of human life of a furnace, A knowledge about the reaction of Al 2 O 3 and the FeO x content slag is important. To characterize the phase equilibria relevant to the slags experimental studies have been carried out to determine liquidus lines of the FeO x -CaO-SiO 2 -Al 2 O 3 -Cr 2 O 3 system with some fixed CaO/SiO 2 mass% ratios and 3.0mass% Cr 2 O 3 at 1573 K. It was found that the influence of the addition of Cr 2 O 3 is small to slag liquidus of Al 2 O 3 -CaO-SiO 2 ternary system. In the measurement range from 0 to 15mass% FeO x , the liquidus line of anorthite primary phase field in the the FeO x -CaO-SiO 2 -Al 2 O 3 -Cr 2 O 3 system does not change with the CaO/SiO 2 ratios of 0.3 to 0.6. On the other hand, the liquid phase was expanded with an increase of the FeO x content except for 0.3 ",

keywords = "Alumina refractory, Anorthite, Erosion, Phase diagram",

author = "Daiki Fujiwara and Hidehiro Sekimoto and Katsunori Yamaguchi",

year = "2017",

month = jan,

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language = "English",

note = "14th International Symposium on East Asian Resources Recycling Technology, EARTH 2017 ; Conference date: 26-09-2017 Through 29-09-2017",

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T1 - [PE1-019] Effect of FeO x on the liquidus line of the Al 2 O 3 -CaO-SiO 2 -Cr 2 O 3 system at 1573K

AU - Fujiwara, Daiki

AU - Sekimoto, Hidehiro

AU - Yamaguchi, Katsunori

PY - 2017/1/1

Y1 - 2017/1/1

N2 - The shredder dust such as an automobile and a home electric appliance is treated in the copper smelting to recover the copper and precious metals in the dust. These secondary materials include combustibles components and chlorine with valuable metals. These are incinerated in rotary kiln furnace to remove combustion and the chlorine of the combustibles component. These are incinerated in rotary kiln furnace to remove combustion and the chlorine of the combustibles component. Refractory including Al 2 O 3 or Cr 2 O 3 is used in the rotary kiln furnace and has strong heat resistance. However, an erosion of the refractory of Al 2 O 3 was sometimes observed with the FeO x -CaO-SiO 2 slag. When we consider prolongation of human life of a furnace, A knowledge about the reaction of Al 2 O 3 and the FeO x content slag is important. To characterize the phase equilibria relevant to the slags experimental studies have been carried out to determine liquidus lines of the FeO x -CaO-SiO 2 -Al 2 O 3 -Cr 2 O 3 system with some fixed CaO/SiO 2 mass% ratios and 3.0mass% Cr 2 O 3 at 1573 K. It was found that the influence of the addition of Cr 2 O 3 is small to slag liquidus of Al 2 O 3 -CaO-SiO 2 ternary system. In the measurement range from 0 to 15mass% FeO x , the liquidus line of anorthite primary phase field in the the FeO x -CaO-SiO 2 -Al 2 O 3 -Cr 2 O 3 system does not change with the CaO/SiO 2 ratios of 0.3 to 0.6. On the other hand, the liquid phase was expanded with an increase of the FeO x content except for 0.3

AB - The shredder dust such as an automobile and a home electric appliance is treated in the copper smelting to recover the copper and precious metals in the dust. These secondary materials include combustibles components and chlorine with valuable metals. These are incinerated in rotary kiln furnace to remove combustion and the chlorine of the combustibles component. These are incinerated in rotary kiln furnace to remove combustion and the chlorine of the combustibles component. Refractory including Al 2 O 3 or Cr 2 O 3 is used in the rotary kiln furnace and has strong heat resistance. However, an erosion of the refractory of Al 2 O 3 was sometimes observed with the FeO x -CaO-SiO 2 slag. When we consider prolongation of human life of a furnace, A knowledge about the reaction of Al 2 O 3 and the FeO x content slag is important. To characterize the phase equilibria relevant to the slags experimental studies have been carried out to determine liquidus lines of the FeO x -CaO-SiO 2 -Al 2 O 3 -Cr 2 O 3 system with some fixed CaO/SiO 2 mass% ratios and 3.0mass% Cr 2 O 3 at 1573 K. It was found that the influence of the addition of Cr 2 O 3 is small to slag liquidus of Al 2 O 3 -CaO-SiO 2 ternary system. In the measurement range from 0 to 15mass% FeO x , the liquidus line of anorthite primary phase field in the the FeO x -CaO-SiO 2 -Al 2 O 3 -Cr 2 O 3 system does not change with the CaO/SiO 2 ratios of 0.3 to 0.6. On the other hand, the liquid phase was expanded with an increase of the FeO x content except for 0.3

KW - Alumina refractory

KW - Anorthite

KW - Erosion

KW - Phase diagram

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