TY - JOUR
T1 - Photo-induced alignment of polymer ultrathin films fabricated by alternate self-assembly solution adsorption of polyelectrolytes and small azo dye chromophores
AU - Advincula, Rigoberto
AU - Fells, Eric
AU - Jones, Nathalie
AU - Guzman, Joanetta
AU - Baba, Akira
AU - Kaneko, Futao
PY - 1999/3
Y1 - 1999/3
N2 - The formation and photo-induced alignment of ultrathin films consisting of small molecular dyes and polyelectrolytes using the alternate solution adsorption technique are described. The small molecular chromophoric dyes were chosen to have sufficient charge density and photoisomerizable azo functional groups. The molecular assembly process of individual polyion-dye pairs were investigated by a number of surface sensitive techniques, including quartz crystal microbalance (QCM), ellipsometry, UV spectroscopy, X-ray reflectometry, XPS, AFM, and surface plasmon spectroscopy. Correlation was made on the effect of film formation parameters to the overall film quality and layer ordering.
AB - The formation and photo-induced alignment of ultrathin films consisting of small molecular dyes and polyelectrolytes using the alternate solution adsorption technique are described. The small molecular chromophoric dyes were chosen to have sufficient charge density and photoisomerizable azo functional groups. The molecular assembly process of individual polyion-dye pairs were investigated by a number of surface sensitive techniques, including quartz crystal microbalance (QCM), ellipsometry, UV spectroscopy, X-ray reflectometry, XPS, AFM, and surface plasmon spectroscopy. Correlation was made on the effect of film formation parameters to the overall film quality and layer ordering.
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M3 - Article
AN - SCOPUS:0033095340
SN - 0032-3934
VL - 40
SP - 443
EP - 444
JO - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
JF - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
IS - 1
ER -