TY - JOUR
T1 - Picosecond pulse radiolysis on geminate ion recombination and formation of solute excited state in liquid cyclohexane
AU - Yoshida, Y.
AU - Tagawa, S.
AU - Washio, M.
AU - Kobayashi, H.
AU - Tabata, Y.
PY - 1989
Y1 - 1989
N2 - The geminate ion recombination and the formation process of solute excited states in solutions of biphenyl were studied in cyclohexane by means of picosecond pulse radiolysis with absorption and emission spectroscopies. The time-dependent behavior of the biphenyl anion was analyzed with the diffusion theory in the solute-solvent system. By applying this analysis to the time-dependent fluorescence from excited states of biphenyl, yields of the excited states through various formation processes were deduced. Also, yield of excited states of cyclohexane in the absence of solutes was estimated.
AB - The geminate ion recombination and the formation process of solute excited states in solutions of biphenyl were studied in cyclohexane by means of picosecond pulse radiolysis with absorption and emission spectroscopies. The time-dependent behavior of the biphenyl anion was analyzed with the diffusion theory in the solute-solvent system. By applying this analysis to the time-dependent fluorescence from excited states of biphenyl, yields of the excited states through various formation processes were deduced. Also, yield of excited states of cyclohexane in the absence of solutes was estimated.
UR - http://www.scopus.com/inward/record.url?scp=50849148189&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=50849148189&partnerID=8YFLogxK
U2 - 10.1016/1359-0197(89)90051-9
DO - 10.1016/1359-0197(89)90051-9
M3 - Article
AN - SCOPUS:50849148189
SN - 1359-0197
VL - 34
SP - 493
EP - 496
JO - International Journal of Radiation Applications and Instrumentation. Part
JF - International Journal of Radiation Applications and Instrumentation. Part
IS - 4
ER -