TY - JOUR
T1 - Poly(2-diphenylamino-1,4-phenylenevinylene)
T2 - Its preparation via chemical vapor deposition polymerization
AU - Takahashi, Yusuke
AU - Kurata, Takashi
AU - Nishide, Hiroyuki
AU - Lee, Chun Young
AU - Do, Eui Doo
AU - Jin, Jung Il
PY - 2006/7
Y1 - 2006/7
N2 - 2,5-Bis(chloromethyl)triphenylamine 1 was prepared and polymerized via the Gilch reaction to give poly(2-diphenylamino-1,4-phenylenevinylene) 2G as a solvent-soluble Φ-conjugated polymer. 1 was also polymerized via the chemical vapor deposition to yield the precursor polymer of 2C, which was heated under vacuum to yield a yellow or brown thin film of 2C on substrates such as glass and a silicon wafer. Spectroscopies of the film supported the formation of the poly (2-diphenylamino-1,4-phenylenevinylene) 2C. The arylamine moiety of the 2C film worked as a functional group like a redox site.
AB - 2,5-Bis(chloromethyl)triphenylamine 1 was prepared and polymerized via the Gilch reaction to give poly(2-diphenylamino-1,4-phenylenevinylene) 2G as a solvent-soluble Φ-conjugated polymer. 1 was also polymerized via the chemical vapor deposition to yield the precursor polymer of 2C, which was heated under vacuum to yield a yellow or brown thin film of 2C on substrates such as glass and a silicon wafer. Spectroscopies of the film supported the formation of the poly (2-diphenylamino-1,4-phenylenevinylene) 2C. The arylamine moiety of the 2C film worked as a functional group like a redox site.
KW - Carbonization
KW - Chemical vapor deposition polymerization
KW - Poly(phenylenevinylene)
KW - Triphenylamine
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U2 - 10.1016/j.stam.2006.05.005
DO - 10.1016/j.stam.2006.05.005
M3 - Article
AN - SCOPUS:33747202746
SN - 1468-6996
VL - 7
SP - 475
EP - 480
JO - Science and Technology of Advanced Materials
JF - Science and Technology of Advanced Materials
IS - 5
ER -