Poly[[4-(N-tert-butyl-N-hydroxyamino)phenyl[acetylene[ and the magnetic property of its radical derivative

Hiroyuki Nishide; Takashi Kaneko; Naoki Yoshioka; Harushisa Akiyama; Masukazu Igarashi; Eishun Tsuchida

Poly[[4-(N-tert-butyl-N-hydroxyamino)phenyl[acetylene[ and the magnetic property of its radical derivative

Hiroyuki Nishide^*, Takashi Kaneko, Naoki Yoshioka, Harushisa Akiyama, Masukazu Igarashi, Eishun Tsuchida

^*Corresponding author for this work

Waseda Research Institute for Science and Engineering

Research output: Contribution to journal › Article › peer-review

41 Citations (Scopus)

Abstract

[4-(N-tert-Butyl-N-hydroxyamino)phenyl]acetylene (7) was synthesized and polymerized to yield a solvent-soluble polyacetylene: poly[[4-(N-tert-butyl-N-hydroxyamino)phenyl ]acetylebe[(8)]. Oxidation of the polymer gave its radical derivative: ESR spectrum showed a broad signal only in the δm_s = ±1 region, and magnetic measurement with a SQUID magnetometer revealed an antiferromagnetic through-space interaction.

Original language	English
Pages (from-to)	4567-4571
Number of pages	5
Journal	Macromolecules
Volume	26
Issue number	17
Publication status	Published - 1993 Jan 1

ASJC Scopus subject areas

Materials Chemistry

Cite this

@article{7127826ebdd041739cc73fccfc58e67f,

title = "Poly[[4-(N-tert-butyl-N-hydroxyamino)phenyl[acetylene[ and the magnetic property of its radical derivative",

abstract = "[4-(N-tert-Butyl-N-hydroxyamino)phenyl]acetylene (7) was synthesized and polymerized to yield a solvent-soluble polyacetylene: poly[[4-(N-tert-butyl-N-hydroxyamino)phenyl ]acetylebe[(8)]. Oxidation of the polymer gave its radical derivative: ESR spectrum showed a broad signal only in the δms = ±1 region, and magnetic measurement with a SQUID magnetometer revealed an antiferromagnetic through-space interaction.",

author = "Hiroyuki Nishide and Takashi Kaneko and Naoki Yoshioka and Harushisa Akiyama and Masukazu Igarashi and Eishun Tsuchida",

year = "1993",

month = jan,

day = "1",

language = "English",

volume = "26",

pages = "4567--4571",

journal = "Macromolecules",

issn = "0024-9297",

publisher = "American Chemical Society",

number = "17",

}

TY - JOUR

T1 - Poly[[4-(N-tert-butyl-N-hydroxyamino)phenyl[acetylene[ and the magnetic property of its radical derivative

AU - Nishide, Hiroyuki

AU - Kaneko, Takashi

AU - Yoshioka, Naoki

AU - Akiyama, Harushisa

AU - Igarashi, Masukazu

AU - Tsuchida, Eishun

PY - 1993/1/1

Y1 - 1993/1/1

N2 - [4-(N-tert-Butyl-N-hydroxyamino)phenyl]acetylene (7) was synthesized and polymerized to yield a solvent-soluble polyacetylene: poly[[4-(N-tert-butyl-N-hydroxyamino)phenyl ]acetylebe[(8)]. Oxidation of the polymer gave its radical derivative: ESR spectrum showed a broad signal only in the δms = ±1 region, and magnetic measurement with a SQUID magnetometer revealed an antiferromagnetic through-space interaction.

AB - [4-(N-tert-Butyl-N-hydroxyamino)phenyl]acetylene (7) was synthesized and polymerized to yield a solvent-soluble polyacetylene: poly[[4-(N-tert-butyl-N-hydroxyamino)phenyl ]acetylebe[(8)]. Oxidation of the polymer gave its radical derivative: ESR spectrum showed a broad signal only in the δms = ±1 region, and magnetic measurement with a SQUID magnetometer revealed an antiferromagnetic through-space interaction.

UR - http://www.scopus.com/inward/record.url?scp=0027649846&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0027649846&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0027649846

SN - 0024-9297

VL - 26

SP - 4567

EP - 4571

JO - Macromolecules

JF - Macromolecules

IS - 17

ER -

Poly[[4-(N-tert-butyl-N-hydroxyamino)phenyl[acetylene[ and the magnetic property of its radical derivative

Abstract

ASJC Scopus subject areas

Other files and links

Fingerprint

Cite this