TY - JOUR
T1 - (Porphinato)iron Complex Incorporated in Lipid Bilayer of Liposome
AU - Tsuchida, Eishun
AU - Serine, Mikiya
AU - Nishide, Hiroyuki
AU - Ohno, Hiroyuki
PY - 1983
Y1 - 1983
N2 - [meso-Tetrakis[α, α, α, α-o-(pivalamido)phenyl]porphinato]iron(II) ([Fe(pfp)]) complex with l-dodecyl-2-methylimidazole (DMI) was incorated into the hydrophobic region of liposome of dimyristoylphosphatidylcholine (DMPC). The ineoporporation was confirmed by 1H-NMR (Fig. 2), 31P-NMR, differential scanning calorimetry (Fig. 4), gel permeation chromatography (Fig. 1), ESR (Fig. 3), and fluorescence (Fig. 5) measurements. The liposome-incorporated [Fe(pfp)] complex formed in the pH 7 aqueous medium at 37°C an oxygen adduct with a life-time of 3 h reversibly.
AB - [meso-Tetrakis[α, α, α, α-o-(pivalamido)phenyl]porphinato]iron(II) ([Fe(pfp)]) complex with l-dodecyl-2-methylimidazole (DMI) was incorated into the hydrophobic region of liposome of dimyristoylphosphatidylcholine (DMPC). The ineoporporation was confirmed by 1H-NMR (Fig. 2), 31P-NMR, differential scanning calorimetry (Fig. 4), gel permeation chromatography (Fig. 1), ESR (Fig. 3), and fluorescence (Fig. 5) measurements. The liposome-incorporated [Fe(pfp)] complex formed in the pH 7 aqueous medium at 37°C an oxygen adduct with a life-time of 3 h reversibly.
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U2 - 10.1246/nikkashi.1983.255
DO - 10.1246/nikkashi.1983.255
M3 - Article
AN - SCOPUS:85010117478
SN - 0369-4577
VL - 1983
SP - 255
EP - 258
JO - Nippon Kagaku Kaishi / Chemical Society of Japan - Chemistry and Industrial Chemistry Journal
JF - Nippon Kagaku Kaishi / Chemical Society of Japan - Chemistry and Industrial Chemistry Journal
IS - 2
ER -