Practical conversion of chlorosilanes into alkoxysilanes without generating HCl

Ryutaro Wakabayashi; Yasushi Sugiura; Toshimichi Shibue; Kazuyuki Kuroda

doi:10.1002/anie.201104948

Practical conversion of chlorosilanes into alkoxysilanes without generating HCl

Ryutaro Wakabayashi, Yasushi Sugiura, Toshimichi Shibue, Kazuyuki Kuroda^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

Alcohol-free: A versatile, efficient, and practical synthesis of alkoxysilanes without generation of HCl involves the reaction of chlorosilanes with unsymmetrical ethers in the presence of a Lewis acid (see scheme). The reaction proceeds through selective cleavage of C-O bonds and is superior to conventional processes. Industrially feasible reagents are used and only one by-product results.

Original language	English
Pages (from-to)	10708-10711
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	45
DOIs	https://doi.org/10.1002/anie.201104948
Publication status	Published - 2011 Nov 4
Externally published	Yes

Keywords

ethers
lewis acids
reaction mechanisms
silanes
synthetic methods

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.201104948

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Practical conversion of chlorosilanes into alkoxysilanes without generating HCl

Abstract

Keywords

ASJC Scopus subject areas

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