Abstract
A method is proposed for predicting the existence of binary azeotropes and their boiling temperatures by use of topological and thermodynamic conditions for combinations of azeotropes in ternary systems. The method can not only predict boiling temperatures but also give their confidence intervals. Its usefulness is demonstrated by predicting azeotropic temperatures of 8 binary systems utilizing 559 sets of ternary azeotropic data.
Original language | English |
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Number of pages | 1 |
Journal | Kagaku Kogaku Ronbunshu |
Volume | 27 |
Issue number | 4 |
Publication status | Published - 2001 Dec 1 |
Externally published | Yes |
Keywords
- Confidence interval
- Consistency test
- Prediction of azeotropes
- Process systems engineering
- Topological condition
ASJC Scopus subject areas
- Chemistry(all)
- Chemical Engineering(all)