Preparation and properties of trans-2-butene-1,4-bis (triphenylphosphonium) -saponite

Yusuke Tanaka; Tomohiko Okada; Makoto Ogawa

doi:10.1007/s10934-006-7025-6

Preparation and properties of trans-2-butene-1,4-bis (triphenylphosphonium) -saponite

Yusuke Tanaka, Tomohiko Okada^*, Makoto Ogawa

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Intercalation of trans-2-butene-1,4-bis(triphenyl phosphonium) into synthetic saponite (Sumecton SA; cation exchange capacity of 71 meq (100 g clay)^-1) was conducted by the cation exchange reaction in aqueous solution. The sample was obtained as powder and thin supported film. Quantitative cation exchange was shown by the chemical composition of the product as well as the amount of the trans-2-butene-1,4- bis(triphenylphosphonium) remaining in the solution. The intercalation compound adsorbed styrene from aqueous solution and exhibited thermal stability (decomposes at higher than 400°C) as shown by the TG-DTA curves recorded in air.

Original language	English
Pages (from-to)	157-161
Number of pages	5
Journal	Journal of Porous Materials
Volume	13
Issue number	2
DOIs	https://doi.org/10.1007/s10934-006-7025-6
Publication status	Published - 2006 Apr

Keywords

Adsorption
Intercalation compound
Synthetic saponite
Trans-2-butene-1, 4-bis (triphenylphosphonium)

ASJC Scopus subject areas

Chemistry (miscellaneous)
Physical and Theoretical Chemistry
Materials Science(all)
Catalysis

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title = "Preparation and properties of trans-2-butene-1,4-bis (triphenylphosphonium) -saponite",

abstract = "Intercalation of trans-2-butene-1,4-bis(triphenyl phosphonium) into synthetic saponite (Sumecton SA; cation exchange capacity of 71 meq (100 g clay)-1) was conducted by the cation exchange reaction in aqueous solution. The sample was obtained as powder and thin supported film. Quantitative cation exchange was shown by the chemical composition of the product as well as the amount of the trans-2-butene-1,4- bis(triphenylphosphonium) remaining in the solution. The intercalation compound adsorbed styrene from aqueous solution and exhibited thermal stability (decomposes at higher than 400°C) as shown by the TG-DTA curves recorded in air.",

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AU - Tanaka, Yusuke

AU - Okada, Tomohiko

AU - Ogawa, Makoto

PY - 2006/4

Y1 - 2006/4

N2 - Intercalation of trans-2-butene-1,4-bis(triphenyl phosphonium) into synthetic saponite (Sumecton SA; cation exchange capacity of 71 meq (100 g clay)-1) was conducted by the cation exchange reaction in aqueous solution. The sample was obtained as powder and thin supported film. Quantitative cation exchange was shown by the chemical composition of the product as well as the amount of the trans-2-butene-1,4- bis(triphenylphosphonium) remaining in the solution. The intercalation compound adsorbed styrene from aqueous solution and exhibited thermal stability (decomposes at higher than 400°C) as shown by the TG-DTA curves recorded in air.

AB - Intercalation of trans-2-butene-1,4-bis(triphenyl phosphonium) into synthetic saponite (Sumecton SA; cation exchange capacity of 71 meq (100 g clay)-1) was conducted by the cation exchange reaction in aqueous solution. The sample was obtained as powder and thin supported film. Quantitative cation exchange was shown by the chemical composition of the product as well as the amount of the trans-2-butene-1,4- bis(triphenylphosphonium) remaining in the solution. The intercalation compound adsorbed styrene from aqueous solution and exhibited thermal stability (decomposes at higher than 400°C) as shown by the TG-DTA curves recorded in air.

KW - Adsorption

KW - Intercalation compound

KW - Synthetic saponite

KW - Trans-2-butene-1, 4-bis (triphenylphosphonium)

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Preparation and properties of trans-2-butene-1,4-bis (triphenylphosphonium) -saponite

Abstract

Keywords

ASJC Scopus subject areas

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