Preparation of electroactive poly (p-phenylene) film by means of electrochemical oxidation and reduction methods

Shinichi Komaba; Toshiyuki Momma; Ami Usui; Tetsuya Osaka

doi:10.5796/kogyobutsurikagaku.65.204

Preparation of electroactive poly (p-phenylene) film by means of electrochemical oxidation and reduction methods

Shinichi Komaba, Toshiyuki Momma, Ami Usui, Tetsuya Osaka

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

We tried to prove the merit of electrochemical reductive polymerization (ERP) original character of which is to control polymerization site on the preparation of π-conjugated polymer film. As the results, an electroactive poly(p-phenylene) film formed by ERP demonstrated a reversible higher redox property and narrower energy band gap in comparison with the film formed by electrochemical oxidative polymerization of biphenyl. So it is efficient to use EPR as the film formation of π-conjugated polymer film.

Original language	English
Pages (from-to)	204-207
Number of pages	4
Journal	Denki Kagaku
Volume	65
Issue number	3
DOIs	https://doi.org/10.5796/kogyobutsurikagaku.65.204
Publication status	Published - 1997
Externally published	Yes

Keywords

Electropolymorization
Poly(p-phonylone)

ASJC Scopus subject areas

Chemistry(all)

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10.5796/kogyobutsurikagaku.65.204

Cite this

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abstract = "We tried to prove the merit of electrochemical reductive polymerization (ERP) original character of which is to control polymerization site on the preparation of π-conjugated polymer film. As the results, an electroactive poly(p-phenylene) film formed by ERP demonstrated a reversible higher redox property and narrower energy band gap in comparison with the film formed by electrochemical oxidative polymerization of biphenyl. So it is efficient to use EPR as the film formation of π-conjugated polymer film.",

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language = "English",

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pages = "204--207",

journal = "Denki Kagaku",

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T1 - Preparation of electroactive poly (p-phenylene) film by means of electrochemical oxidation and reduction methods

AU - Komaba, Shinichi

AU - Momma, Toshiyuki

AU - Usui, Ami

AU - Osaka, Tetsuya

PY - 1997

Y1 - 1997

N2 - We tried to prove the merit of electrochemical reductive polymerization (ERP) original character of which is to control polymerization site on the preparation of π-conjugated polymer film. As the results, an electroactive poly(p-phenylene) film formed by ERP demonstrated a reversible higher redox property and narrower energy band gap in comparison with the film formed by electrochemical oxidative polymerization of biphenyl. So it is efficient to use EPR as the film formation of π-conjugated polymer film.

AB - We tried to prove the merit of electrochemical reductive polymerization (ERP) original character of which is to control polymerization site on the preparation of π-conjugated polymer film. As the results, an electroactive poly(p-phenylene) film formed by ERP demonstrated a reversible higher redox property and narrower energy band gap in comparison with the film formed by electrochemical oxidative polymerization of biphenyl. So it is efficient to use EPR as the film formation of π-conjugated polymer film.

KW - Electropolymorization

KW - Poly(p-phonylone)

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UR - http://www.scopus.com/inward/citedby.url?scp=0039070040&partnerID=8YFLogxK

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SP - 204

EP - 207

JO - Denki Kagaku

JF - Denki Kagaku

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Preparation of electroactive poly (p-phenylene) film by means of electrochemical oxidation and reduction methods

Abstract

Keywords

ASJC Scopus subject areas

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