TY - JOUR
T1 - Preparation of V2O5 gel-viologen intercalation compounds
AU - Nakato, Teruyuki
AU - Kato, Ikuo
AU - Kuroda, Kazuyuki
AU - Kato, Chuzo
N1 - Funding Information:
One of the authors (K.K.) expresses his sincere thanks to Nippon Sheet Glass Foundation for the financial support. Science and Engineering Research Laboratory of Waseda University also supported this Project Study.
PY - 1989/12
Y1 - 1989/12
N2 - Methyl, heptyl, and benzyl viologens were intercalated into the interlayer space of vanadium pentoxide gel (V2O5 · nH2O) by ion exchange. Intercalated methyl and benzyl viologens were present in monolayer arrangements in which the viologens lie parallel to the oxide layer. Heptyl viologens were intercalated in a transversal arrangement with respect to the host layer. The difference among those arrangements in the interlayer region was ascribed to the different sizes of the dications used.
AB - Methyl, heptyl, and benzyl viologens were intercalated into the interlayer space of vanadium pentoxide gel (V2O5 · nH2O) by ion exchange. Intercalated methyl and benzyl viologens were present in monolayer arrangements in which the viologens lie parallel to the oxide layer. Heptyl viologens were intercalated in a transversal arrangement with respect to the host layer. The difference among those arrangements in the interlayer region was ascribed to the different sizes of the dications used.
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U2 - 10.1016/S0021-9797(89)80055-4
DO - 10.1016/S0021-9797(89)80055-4
M3 - Article
AN - SCOPUS:0000299193
SN - 0021-9797
VL - 133
SP - 447
EP - 451
JO - Journal of Colloid And Interface Science
JF - Journal of Colloid And Interface Science
IS - 2
ER -