Pulse radiolysis studies on the transient species of aromatic molecules in chlorinated hydrocarbon solutions

Masakazu Washio; Seiichi Tagawa; Kazuo Furuya; Nariyuki Hayashi; Yoneho Tabata

Pulse radiolysis studies on the transient species of aromatic molecules in chlorinated hydrocarbon solutions

Masakazu Washio^*, Seiichi Tagawa, Kazuo Furuya, Nariyuki Hayashi, Yoneho Tabata

^*Corresponding author for this work

Research output: Contribution to journal › Conference article › peer-review

7 Citations (Scopus)

Abstract

Pulse radiolysis has been carried out to identify the transient species produced by the pulsed electron irradiation for the several kinds of combination of the solutions of aromatic hydrocarbons (benzene, naphthalene and pyrene) in chlorinated hydrocarbons (CCl₄, CHCl₃, and CH₂Cl₂). Charge-transfer complex between aromatic ring and Cl atom has been observed for benzene solutions in above three solvents. Naphthalene monomer and dimer cation radicals have been observed for the solutions in CHCl₃ and CH₂Cl₂. Monomer cation radicals of pyrene has been observed for the solution of pyrene in CCl₄, and monomer and dimer cation radicals of pyrene have been observed for the solutions in CHCl₃ and CH₂Cl₂.

Original language	English
Pages (from-to)	533-537
Number of pages	5
Journal	Radiation Physics and Chemistry
Volume	34
Issue number	4
Publication status	Published - 1989 Dec 1
Externally published	Yes
Event	Proceedings of an International Symposium on Fast Excitation Processes - Tokyo, Jpn Duration: 1988 Mar 21 → 1988 Mar 25

ASJC Scopus subject areas

Radiation

Cite this

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title = "Pulse radiolysis studies on the transient species of aromatic molecules in chlorinated hydrocarbon solutions",

abstract = "Pulse radiolysis has been carried out to identify the transient species produced by the pulsed electron irradiation for the several kinds of combination of the solutions of aromatic hydrocarbons (benzene, naphthalene and pyrene) in chlorinated hydrocarbons (CCl4, CHCl3, and CH2Cl2). Charge-transfer complex between aromatic ring and Cl atom has been observed for benzene solutions in above three solvents. Naphthalene monomer and dimer cation radicals have been observed for the solutions in CHCl3 and CH2Cl2. Monomer cation radicals of pyrene has been observed for the solution of pyrene in CCl4, and monomer and dimer cation radicals of pyrene have been observed for the solutions in CHCl3 and CH2Cl2.",

author = "Masakazu Washio and Seiichi Tagawa and Kazuo Furuya and Nariyuki Hayashi and Yoneho Tabata",

year = "1989",

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pages = "533--537",

journal = "Radiation Physics and Chemistry",

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note = "Proceedings of an International Symposium on Fast Excitation Processes ; Conference date: 21-03-1988 Through 25-03-1988",

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T1 - Pulse radiolysis studies on the transient species of aromatic molecules in chlorinated hydrocarbon solutions

AU - Washio, Masakazu

AU - Tagawa, Seiichi

AU - Furuya, Kazuo

AU - Hayashi, Nariyuki

AU - Tabata, Yoneho

PY - 1989/12/1

Y1 - 1989/12/1

N2 - Pulse radiolysis has been carried out to identify the transient species produced by the pulsed electron irradiation for the several kinds of combination of the solutions of aromatic hydrocarbons (benzene, naphthalene and pyrene) in chlorinated hydrocarbons (CCl4, CHCl3, and CH2Cl2). Charge-transfer complex between aromatic ring and Cl atom has been observed for benzene solutions in above three solvents. Naphthalene monomer and dimer cation radicals have been observed for the solutions in CHCl3 and CH2Cl2. Monomer cation radicals of pyrene has been observed for the solution of pyrene in CCl4, and monomer and dimer cation radicals of pyrene have been observed for the solutions in CHCl3 and CH2Cl2.

AB - Pulse radiolysis has been carried out to identify the transient species produced by the pulsed electron irradiation for the several kinds of combination of the solutions of aromatic hydrocarbons (benzene, naphthalene and pyrene) in chlorinated hydrocarbons (CCl4, CHCl3, and CH2Cl2). Charge-transfer complex between aromatic ring and Cl atom has been observed for benzene solutions in above three solvents. Naphthalene monomer and dimer cation radicals have been observed for the solutions in CHCl3 and CH2Cl2. Monomer cation radicals of pyrene has been observed for the solution of pyrene in CCl4, and monomer and dimer cation radicals of pyrene have been observed for the solutions in CHCl3 and CH2Cl2.

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M3 - Conference article

AN - SCOPUS:0024933073

SN - 0969-806X

VL - 34

SP - 533

EP - 537

JO - Radiation Physics and Chemistry

JF - Radiation Physics and Chemistry

IS - 4

T2 - Proceedings of an International Symposium on Fast Excitation Processes

Y2 - 21 March 1988 through 25 March 1988

ER -

Pulse radiolysis studies on the transient species of aromatic molecules in chlorinated hydrocarbon solutions

Abstract

ASJC Scopus subject areas

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