TY - JOUR
T1 - Reaction of a stable digermyne with acetylenes
T2 - Synthesis of a 1,2-digermabenzene and a 1,4-digermabarrelene#
AU - Sugahara, Tomohiro
AU - Guo, Jing Dong
AU - Sasamori, Takahiro
AU - Karatsu, Yusaku
AU - Furukawa, Yukio
AU - Ferao, Arturo Espinosa
AU - Nagase, Shigeru
AU - Tokitoh, Norihiro
N1 - Publisher Copyright:
© 2016 The Chemical Society of Japan.
PY - 2016
Y1 - 2016
N2 - Reactions between acetylenes and a stable digermyne bearing 4-t-Bu-2,6-[CH(SiMe3)2]2-C6H2 (Tbb) groups afforded the corresponding stable 1,2-digermabenzenes together with the respective 1,4-digermabarrelenes. The properties of the obtained products and the reaction mechanism are discussed on the basis of experimental and theoretical results. Especially, the aromaticity of the newly obtained 1,2-digermabenzene has been discussed on the detailed calculations, revealing its aromatic character to some degree.
AB - Reactions between acetylenes and a stable digermyne bearing 4-t-Bu-2,6-[CH(SiMe3)2]2-C6H2 (Tbb) groups afforded the corresponding stable 1,2-digermabenzenes together with the respective 1,4-digermabarrelenes. The properties of the obtained products and the reaction mechanism are discussed on the basis of experimental and theoretical results. Especially, the aromaticity of the newly obtained 1,2-digermabenzene has been discussed on the detailed calculations, revealing its aromatic character to some degree.
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U2 - 10.1246/bcsj.20160269
DO - 10.1246/bcsj.20160269
M3 - Article
AN - SCOPUS:85025805317
SN - 0009-2673
VL - 89
SP - 1375
EP - 1384
JO - Bulletin of the Chemical Society of Japan
JF - Bulletin of the Chemical Society of Japan
IS - 11
ER -