TY - JOUR
T1 - Recent Advances of Biphenylene
T2 - Synthesis, Reactions and Uses
AU - Takano, Hideaki
AU - Ito, Takeharu
AU - Kanyiva, Kyalo Stephen
AU - Shibata, Takanori
N1 - Funding Information:
H. T. is grateful to the Japan Society for the Promotion of Science for the fellowship support. This work was supported by Waseda University Grant for Special Research Projects.
Funding Information:
Hideaki Takano was born in 1992 in Saitama, Japan. He received his BS (2015) and MS (2017) from Waseda University. Supported by Japan Society for the Promotion of Science (JSPS) Overseas Challenge Program for Young Researchers, he joined the group of Dr. Robert. J. Phipps at University of Cambridge as a visiting student. His current research focuses on C-C bond activation reaction by transition metal catalysts for his PhD. degree in the group of Prof. Shibata with a Research Fellowship for Young Scientists (DC2) by JSPS.
Publisher Copyright:
© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
PY - 2019/5/15
Y1 - 2019/5/15
N2 - Biphenylene is an antiaromatic compound that has a strained butadiene skeleton that joins two benzene rings. Various methods for synthesizing the biphenylene core have been developed. In addition, the reactivity of biphenylene has attracted much attention because C–C bonds of biphenylene can be cleaved by various organometallic species. Furthermore, the biphenylene motif not only acts as a spacer in a variety of functional molecules, but also serves as a backbone for catalysts and ligands. This minireview summarizes how to construct the biphenylene structure, how to react biphenylene, and how to use the biphenylene skeleton in functional materials.
AB - Biphenylene is an antiaromatic compound that has a strained butadiene skeleton that joins two benzene rings. Various methods for synthesizing the biphenylene core have been developed. In addition, the reactivity of biphenylene has attracted much attention because C–C bonds of biphenylene can be cleaved by various organometallic species. Furthermore, the biphenylene motif not only acts as a spacer in a variety of functional molecules, but also serves as a backbone for catalysts and ligands. This minireview summarizes how to construct the biphenylene structure, how to react biphenylene, and how to use the biphenylene skeleton in functional materials.
KW - Biphenylene
KW - C–C activation
KW - Hydrocarbons
KW - Metallacycles
KW - Strained molecules
UR - http://www.scopus.com/inward/record.url?scp=85063297473&partnerID=8YFLogxK
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U2 - 10.1002/ejoc.201900111
DO - 10.1002/ejoc.201900111
M3 - Review article
AN - SCOPUS:85063297473
SN - 1434-193X
VL - 2019
SP - 2871
EP - 2883
JO - Justus Liebigs Annalen der Chemie
JF - Justus Liebigs Annalen der Chemie
IS - 18
ER -