Redox property of photo-crosslinked poly(TEMPO-substituted norbornene)s

Hiroaki Konishi; Takeo Suga; Hiroyuki Nishide

Redox property of photo-crosslinked poly(TEMPO-substituted norbornene)s

Hiroaki Konishi^*, Takeo Suga, Hiroyuki Nishide

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to conference › Paper › peer-review

Abstract

Poly(TEMPO-substituted norbornene) was synthesized by ring-opening metathesis polymerization by using Grubbs catalyst. The polymer was photo-crosslinked by bisazide or oxetane derivatives, and applied to an electrode-active material. The obtained radical thin film displayed a stable redox behavior at 3.6V vs. Li/Li⁺.The test cell was fabricated with the polymer cathode and lithium anode.No deterioration of the capacity was observed after 500 cycles.

Original language	English
Number of pages	1
Publication status	Published - 2006 Dec 1
Event	55th Society of Polymer Science Japan Symposium on Macromolecules - Toyama, Japan Duration: 2006 Sept 20 → 2006 Sept 22

Other

Other	55th Society of Polymer Science Japan Symposium on Macromolecules
Country/Territory	Japan
City	Toyama
Period	06/9/20 → 06/9/22

Keywords

Electrode-active material
Nitroxide radical
Photo-crosslinking
Polynorbornene
Secondary battery

ASJC Scopus subject areas

Engineering(all)

Cite this

@conference{ba0027bc795548849c4d984d3b1d92ba,

title = "Redox property of photo-crosslinked poly(TEMPO-substituted norbornene)s",

abstract = "Poly(TEMPO-substituted norbornene) was synthesized by ring-opening metathesis polymerization by using Grubbs catalyst. The polymer was photo-crosslinked by bisazide or oxetane derivatives, and applied to an electrode-active material. The obtained radical thin film displayed a stable redox behavior at 3.6V vs. Li/Li+.The test cell was fabricated with the polymer cathode and lithium anode.No deterioration of the capacity was observed after 500 cycles.",

keywords = "Electrode-active material, Nitroxide radical, Photo-crosslinking, Polynorbornene, Secondary battery",

author = "Hiroaki Konishi and Takeo Suga and Hiroyuki Nishide",

year = "2006",

month = dec,

day = "1",

language = "English",

note = "55th Society of Polymer Science Japan Symposium on Macromolecules ; Conference date: 20-09-2006 Through 22-09-2006",

}

TY - CONF

T1 - Redox property of photo-crosslinked poly(TEMPO-substituted norbornene)s

AU - Konishi, Hiroaki

AU - Suga, Takeo

AU - Nishide, Hiroyuki

PY - 2006/12/1

Y1 - 2006/12/1

N2 - Poly(TEMPO-substituted norbornene) was synthesized by ring-opening metathesis polymerization by using Grubbs catalyst. The polymer was photo-crosslinked by bisazide or oxetane derivatives, and applied to an electrode-active material. The obtained radical thin film displayed a stable redox behavior at 3.6V vs. Li/Li+.The test cell was fabricated with the polymer cathode and lithium anode.No deterioration of the capacity was observed after 500 cycles.

AB - Poly(TEMPO-substituted norbornene) was synthesized by ring-opening metathesis polymerization by using Grubbs catalyst. The polymer was photo-crosslinked by bisazide or oxetane derivatives, and applied to an electrode-active material. The obtained radical thin film displayed a stable redox behavior at 3.6V vs. Li/Li+.The test cell was fabricated with the polymer cathode and lithium anode.No deterioration of the capacity was observed after 500 cycles.

KW - Electrode-active material

KW - Nitroxide radical

KW - Photo-crosslinking

KW - Polynorbornene

KW - Secondary battery

UR - http://www.scopus.com/inward/record.url?scp=33846176060&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33846176060&partnerID=8YFLogxK

M3 - Paper

AN - SCOPUS:33846176060

T2 - 55th Society of Polymer Science Japan Symposium on Macromolecules

Y2 - 20 September 2006 through 22 September 2006

ER -

Redox property of photo-crosslinked poly(TEMPO-substituted norbornene)s

Abstract

Other

Keywords

ASJC Scopus subject areas

Other files and links

Fingerprint

Cite this