Rh(III)-catalyzed directed C-H bond amidation of ferrocenes with isocyanates

Satoshi Takebayashi; Tsubasa Shizuno; Takashi Otani; Takanori Shibata

doi:10.3762/bjoc.8.212

Rh(III)-catalyzed directed C-H bond amidation of ferrocenes with isocyanates

Satoshi Takebayashi, Tsubasa Shizuno, Takashi Otani, Takanori Shibata^*

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

43 Citations (Scopus)

Abstract

[RhCp*(OAc) ₂(H ₂O)] [Cp* = pentamethylcyclopentadienyl] catalyzed the C-H bond amidation of ferrocenes possessing directing groups with isocyanates in the presence of 2 equiv/Rh of HBF4·OEt2. A variety of disubstituted ferrocenes were prepared in high yields, or excellent diastereoselectivities.

Original language	English
Pages (from-to)	1844-1848
Number of pages	5
Journal	Beilstein Journal of Organic Chemistry
Volume	8
DOIs	https://doi.org/10.3762/bjoc.8.212
Publication status	Published - 2012 Oct 29

Keywords

Amidation
C-H activation
C-H functionalization
Ferrocene
Rhodium

ASJC Scopus subject areas

Organic Chemistry

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10.3762/bjoc.8.212

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title = "Rh(III)-catalyzed directed C-H bond amidation of ferrocenes with isocyanates",

abstract = "[RhCp*(OAc) 2(H 2O)] [Cp* = pentamethylcyclopentadienyl] catalyzed the C-H bond amidation of ferrocenes possessing directing groups with isocyanates in the presence of 2 equiv/Rh of HBF4·OEt2. A variety of disubstituted ferrocenes were prepared in high yields, or excellent diastereoselectivities.",

keywords = "Amidation, C-H activation, C-H functionalization, Ferrocene, Rhodium",

author = "Satoshi Takebayashi and Tsubasa Shizuno and Takashi Otani and Takanori Shibata",

year = "2012",

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day = "29",

doi = "10.3762/bjoc.8.212",

language = "English",

volume = "8",

pages = "1844--1848",

journal = "Beilstein Journal of Organic Chemistry",

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T1 - Rh(III)-catalyzed directed C-H bond amidation of ferrocenes with isocyanates

AU - Takebayashi, Satoshi

AU - Shizuno, Tsubasa

AU - Otani, Takashi

AU - Shibata, Takanori

PY - 2012/10/29

Y1 - 2012/10/29

N2 - [RhCp*(OAc) 2(H 2O)] [Cp* = pentamethylcyclopentadienyl] catalyzed the C-H bond amidation of ferrocenes possessing directing groups with isocyanates in the presence of 2 equiv/Rh of HBF4·OEt2. A variety of disubstituted ferrocenes were prepared in high yields, or excellent diastereoselectivities.

AB - [RhCp*(OAc) 2(H 2O)] [Cp* = pentamethylcyclopentadienyl] catalyzed the C-H bond amidation of ferrocenes possessing directing groups with isocyanates in the presence of 2 equiv/Rh of HBF4·OEt2. A variety of disubstituted ferrocenes were prepared in high yields, or excellent diastereoselectivities.

KW - Amidation

KW - C-H activation

KW - C-H functionalization

KW - Ferrocene

KW - Rhodium

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SN - 1860-5397

VL - 8

SP - 1844

EP - 1848

JO - Beilstein Journal of Organic Chemistry

JF - Beilstein Journal of Organic Chemistry

ER -

Rh(III)-catalyzed directed C-H bond amidation of ferrocenes with isocyanates

Abstract

Keywords

ASJC Scopus subject areas

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