Rhodium-catalyzed intramolecular cycloaddition of cyclopropene-ynes triggered by cabon-carbon bond cleavage

Takanori Shibata; Shunsuke Maekawa; Kohei Tamura

doi:10.3987/COM-08-S(N)92

Rhodium-catalyzed intramolecular cycloaddition of cyclopropene-ynes triggered by cabon-carbon bond cleavage

Takanori Shibata^*, Shunsuke Maekawa, Kohei Tamura

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

In the presence of a catalytic amount of RhCI(PPh₃)₃, an intramolecular cycloaddition of cyclopropene-yne proceeded along with carbon-carbon bond cleavage of cyclopropene ring to give various bicyclic cyclopentadiene derivatives in good to high yield.

Original language	English
Pages (from-to)	1261-1270
Number of pages	10
Journal	Heterocycles
Volume	76
Issue number	2
DOIs	https://doi.org/10.3987/COM-08-S(N)92
Publication status	Published - 2008 Nov 1

Keywords

Bond Cleavage
Cycloaddition
Cyclopentadiene
Cyclopropene
Rhodium

ASJC Scopus subject areas

Analytical Chemistry
Pharmacology
Organic Chemistry

Access to Document

10.3987/COM-08-S(N)92

Cite this

@article{5bf57a936e8d42038e367b84fb050834,

title = "Rhodium-catalyzed intramolecular cycloaddition of cyclopropene-ynes triggered by cabon-carbon bond cleavage",

abstract = "In the presence of a catalytic amount of RhCI(PPh3)3, an intramolecular cycloaddition of cyclopropene-yne proceeded along with carbon-carbon bond cleavage of cyclopropene ring to give various bicyclic cyclopentadiene derivatives in good to high yield.",

keywords = "Bond Cleavage, Cycloaddition, Cyclopentadiene, Cyclopropene, Rhodium",

author = "Takanori Shibata and Shunsuke Maekawa and Kohei Tamura",

year = "2008",

month = nov,

day = "1",

doi = "10.3987/COM-08-S(N)92",

language = "English",

volume = "76",

pages = "1261--1270",

journal = "Heterocycles",

issn = "0385-5414",

publisher = "Japan Institute of Heterocyclic Chemistry",

number = "2",

}

TY - JOUR

T1 - Rhodium-catalyzed intramolecular cycloaddition of cyclopropene-ynes triggered by cabon-carbon bond cleavage

AU - Shibata, Takanori

AU - Maekawa, Shunsuke

AU - Tamura, Kohei

PY - 2008/11/1

Y1 - 2008/11/1

N2 - In the presence of a catalytic amount of RhCI(PPh3)3, an intramolecular cycloaddition of cyclopropene-yne proceeded along with carbon-carbon bond cleavage of cyclopropene ring to give various bicyclic cyclopentadiene derivatives in good to high yield.

AB - In the presence of a catalytic amount of RhCI(PPh3)3, an intramolecular cycloaddition of cyclopropene-yne proceeded along with carbon-carbon bond cleavage of cyclopropene ring to give various bicyclic cyclopentadiene derivatives in good to high yield.

KW - Bond Cleavage

KW - Cycloaddition

KW - Cyclopentadiene

KW - Cyclopropene

KW - Rhodium

UR - http://www.scopus.com/inward/record.url?scp=61349097341&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=61349097341&partnerID=8YFLogxK

U2 - 10.3987/COM-08-S(N)92

DO - 10.3987/COM-08-S(N)92

M3 - Article

AN - SCOPUS:61349097341

SN - 0385-5414

VL - 76

SP - 1261

EP - 1270

JO - Heterocycles

JF - Heterocycles

IS - 2

ER -

Rhodium-catalyzed intramolecular cycloaddition of cyclopropene-ynes triggered by cabon-carbon bond cleavage

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this