Ru-catalyzed β-selective and enantioselective addition of amines to styrenes initiated by direct arene-exchange

Maiko Otsuka; Hiroya Yokoyama; Kohei Endo; Takanori Shibata

doi:10.1039/c2ob25457c

Ru-catalyzed β-selective and enantioselective addition of amines to styrenes initiated by direct arene-exchange

Maiko Otsuka, Hiroya Yokoyama, Kohei Endo, Takanori Shibata^*

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

A catalytic β-selective addition of amines to styrenes proceeded in the presence of cationic Ru complexes combined with diphosphine ligands. In the reaction of α-methylstyrene, an enantioselective addition was achieved by using xylylBINAP.

Original language	English
Pages (from-to)	3815-3818
Number of pages	4
Journal	Organic and Biomolecular Chemistry
Volume	10
Issue number	19
DOIs	https://doi.org/10.1039/c2ob25457c
Publication status	Published - 2012 May 21

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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title = "Ru-catalyzed β-selective and enantioselective addition of amines to styrenes initiated by direct arene-exchange",

abstract = "A catalytic β-selective addition of amines to styrenes proceeded in the presence of cationic Ru complexes combined with diphosphine ligands. In the reaction of α-methylstyrene, an enantioselective addition was achieved by using xylylBINAP.",

author = "Maiko Otsuka and Hiroya Yokoyama and Kohei Endo and Takanori Shibata",

year = "2012",

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doi = "10.1039/c2ob25457c",

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journal = "Organic and Biomolecular Chemistry",

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T1 - Ru-catalyzed β-selective and enantioselective addition of amines to styrenes initiated by direct arene-exchange

AU - Otsuka, Maiko

AU - Yokoyama, Hiroya

AU - Endo, Kohei

AU - Shibata, Takanori

PY - 2012/5/21

Y1 - 2012/5/21

N2 - A catalytic β-selective addition of amines to styrenes proceeded in the presence of cationic Ru complexes combined with diphosphine ligands. In the reaction of α-methylstyrene, an enantioselective addition was achieved by using xylylBINAP.

AB - A catalytic β-selective addition of amines to styrenes proceeded in the presence of cationic Ru complexes combined with diphosphine ligands. In the reaction of α-methylstyrene, an enantioselective addition was achieved by using xylylBINAP.

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AN - SCOPUS:84860359398

SN - 1477-0520

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JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 19

ER -

Ru-catalyzed β-selective and enantioselective addition of amines to styrenes initiated by direct arene-exchange

Abstract

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