TY - JOUR
T1 - Solid-state intercalation of acrylamide into smectites and Na-taeniolite
AU - Ogawa, Makoto
AU - Nagafusa, Yasuyuki
AU - Kuroda, Kazuyuki
AU - Kato, Chuzo
N1 - Funding Information:
The present work was partially supported by a Grant-in-Aid for Scientific Research from the Ministry of Education, Science and Culture. Waseda University also provided financial support under the Special Project Research Scheme.
PY - 1992/11
Y1 - 1992/11
N2 - Various clay minerals of the smectite group could form intercalation compounds with acrylamide by solid-solid reaction at room temperature and within a few minutes of contacting the reactants. Taeniolite, a synthetic fluor-mica with a higher layer charge density than smectites, gave an only incomplete intercalation. The propensity of the minerals for intercalating acrylamide was correlated with their reactivity towards ethylene glycol. Because of their rapidity and simplicity, solid-solid reactions provide a new way of introducing organic species into the interlayer spaces of smectites.
AB - Various clay minerals of the smectite group could form intercalation compounds with acrylamide by solid-solid reaction at room temperature and within a few minutes of contacting the reactants. Taeniolite, a synthetic fluor-mica with a higher layer charge density than smectites, gave an only incomplete intercalation. The propensity of the minerals for intercalating acrylamide was correlated with their reactivity towards ethylene glycol. Because of their rapidity and simplicity, solid-solid reactions provide a new way of introducing organic species into the interlayer spaces of smectites.
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U2 - 10.1016/0169-1317(92)90016-G
DO - 10.1016/0169-1317(92)90016-G
M3 - Article
AN - SCOPUS:0027007629
SN - 0169-1317
VL - 7
SP - 291
EP - 302
JO - Applied Clay Science
JF - Applied Clay Science
IS - 4
ER -