Specific oxygen-binding to a polymer-supported N, N′-disalicylidenethylenediaminocobalt complex

Hiroyuki Nishide*, Erichi Soda, Hiroyuki Mizuma, Eishun Tsuchida

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

A polymer membrane containing N, N′-disalicylidenethylene-diaminocobalt (Co(salen)) was prepared. The Co(salen) supported in the polymer not only worked as a reversible and specific oxygen-adsorbent but discontinuously bound oxygen at the atmospheric oxygen partial pressure of ca 15 cmHg to give an on-off-like oxygen-binding curve. Oxygen permeation through the Co(salen) membrane was also augmented in the higher upstream oxygen pressure region, which was caused by the specific oxygen-binding to the Co(saten) fixed in the membrane.

Original languageEnglish
Pages (from-to)191-197
Number of pages7
JournalMacromolecular Symposia
Volume105
Publication statusPublished - 1996 Mar

ASJC Scopus subject areas

  • Materials Chemistry
  • Polymers and Plastics

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