Standard Gibbs energies of formation of SiCl2(g) and SiCl3(g) species at 1000 to 1300 K

Masaki Kanamori; Masahito Sugiura; Akio Fuwa

Standard Gibbs energies of formation of SiCl₂(g) and SiCl₃(g) species at 1000 to 1300 K

Masaki Kanamori^*, Masahito Sugiura, Akio Fuwa

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The equilibria in the Si(s)-Cl₂(g) system have been studied at temperature from 1000 to 1300 K using a transpiration reactor. The equilibria are considered among Si(s)-Cl₂(g)-SiCl₂(g)-SiCl₃(g)-SiCl₄(g). The standard Gibbs energies of formation for the species of SiCl₂(g) and SiCl₃(g) species at these temperatures are determined simultaneously, where these subchloride species coexist in appreciable quantities with SiCl₄ in the gas phase at these temperatures, as follows: SiCl₂(g): ΔG°_{f·SiCl(2)·T}(1000-1300 K)=-185.0-2.32×10^-2 T kJ·mol^-1 SiCl₃(g): ΔG°_{f·SiCl(3)·T}(1000-1300 K)=-401.1+3.28×10^-2 T kJ·mol^-1

Original language	English
Pages (from-to)	156-163
Number of pages	8
Journal	Nippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals
Volume	59
Issue number	2
Publication status	Published - 1995 Feb

ASJC Scopus subject areas

Metals and Alloys

Cite this

@article{c118430aa8344c38b83bf196efd1da26,

title = "Standard Gibbs energies of formation of SiCl2(g) and SiCl3(g) species at 1000 to 1300 K",

abstract = "The equilibria in the Si(s)-Cl2(g) system have been studied at temperature from 1000 to 1300 K using a transpiration reactor. The equilibria are considered among Si(s)-Cl2(g)-SiCl2(g)-SiCl3(g)-SiCl4(g). The standard Gibbs energies of formation for the species of SiCl2(g) and SiCl3(g) species at these temperatures are determined simultaneously, where these subchloride species coexist in appreciable quantities with SiCl4 in the gas phase at these temperatures, as follows: SiCl2(g): ΔG°f·SiCl(2)·T(1000-1300 K)=-185.0-2.32×10-2 T kJ·mol-1 SiCl3(g): ΔG°f·SiCl(3)·T(1000-1300 K)=-401.1+3.28×10-2 T kJ·mol-1 ",

author = "Masaki Kanamori and Masahito Sugiura and Akio Fuwa",

year = "1995",

month = feb,

language = "English",

volume = "59",

pages = "156--163",

journal = "Nippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals",

issn = "0021-4876",

publisher = "Japan Institute of Metals (JIM)",

number = "2",

}

TY - JOUR

T1 - Standard Gibbs energies of formation of SiCl2(g) and SiCl3(g) species at 1000 to 1300 K

AU - Kanamori, Masaki

AU - Sugiura, Masahito

AU - Fuwa, Akio

PY - 1995/2

Y1 - 1995/2

N2 - The equilibria in the Si(s)-Cl2(g) system have been studied at temperature from 1000 to 1300 K using a transpiration reactor. The equilibria are considered among Si(s)-Cl2(g)-SiCl2(g)-SiCl3(g)-SiCl4(g). The standard Gibbs energies of formation for the species of SiCl2(g) and SiCl3(g) species at these temperatures are determined simultaneously, where these subchloride species coexist in appreciable quantities with SiCl4 in the gas phase at these temperatures, as follows: SiCl2(g): ΔG°f·SiCl(2)·T(1000-1300 K)=-185.0-2.32×10-2 T kJ·mol-1 SiCl3(g): ΔG°f·SiCl(3)·T(1000-1300 K)=-401.1+3.28×10-2 T kJ·mol-1

AB - The equilibria in the Si(s)-Cl2(g) system have been studied at temperature from 1000 to 1300 K using a transpiration reactor. The equilibria are considered among Si(s)-Cl2(g)-SiCl2(g)-SiCl3(g)-SiCl4(g). The standard Gibbs energies of formation for the species of SiCl2(g) and SiCl3(g) species at these temperatures are determined simultaneously, where these subchloride species coexist in appreciable quantities with SiCl4 in the gas phase at these temperatures, as follows: SiCl2(g): ΔG°f·SiCl(2)·T(1000-1300 K)=-185.0-2.32×10-2 T kJ·mol-1 SiCl3(g): ΔG°f·SiCl(3)·T(1000-1300 K)=-401.1+3.28×10-2 T kJ·mol-1

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M3 - Article

AN - SCOPUS:0029252190

SN - 0021-4876

VL - 59

SP - 156

EP - 163

JO - Nippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals

JF - Nippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals

IS - 2

ER -

Standard Gibbs energies of formation of SiCl₂(g) and SiCl₃(g) species at 1000 to 1300 K

Abstract

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