Synthesis and characterization of microporous layered zirconium phenylphosphonate

N. K. Mal; M. Sasidharan; M. Fujiwara; Y. Yamada; M. Matsukata

Synthesis and characterization of microporous layered zirconium phenylphosphonate

N. K. Mal^*, M. Sasidharan, M. Fujiwara, Y. Yamada, M. Matsukata

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Microporous layered zirconium phenylphosphonate, Zr(O₃P-C ₆H₅)₂ was prepared in presence of sodium dodecylsulfate (SDS), for the first time. Interplanar spacing (d₀₀₁) and surface area of microporous zirconium phenylphosphonate are 1.47 nm and 198 m²g^-1, respectively. FT-IR spectrum indicates absence or negligible amount of hydroxyls groups in zirconium phenylphosphonate sample, ³¹P solid MAS NMR also confirms the presence of trace amount of hydroxyl groups in zirconium phenylphosphonate. The presence of tetra-coordinated phosphorous ions and hexa-coordinated zirconium ions were realized by the ³¹P solid MAS NMR and UV-visible, respectively. Sulfonated derivative of zirconium phenylphosphonate, Zr(O₃PC ₆H₄SO₃H)₁₉ (O₃PC ₆H₅)_0.1·3.7H₂O were also prepared.

Original language	English
Pages (from-to)	1153-1159
Number of pages	7
Journal	Studies in Surface Science and Catalysis
Volume	154 A
Publication status	Published - 2004 Jan 1

Keywords

Layered
Mircroporous material
Sodium dodecylsulfate
Zirconium phenylphosphonate

ASJC Scopus subject areas

Catalysis
Condensed Matter Physics
Physical and Theoretical Chemistry
Surfaces, Coatings and Films
Materials Chemistry

Cite this

@article{a6ec5d71c473494bbd767cfc86777ef2,

title = "Synthesis and characterization of microporous layered zirconium phenylphosphonate",

abstract = "Microporous layered zirconium phenylphosphonate, Zr(O3P-C 6H5)2 was prepared in presence of sodium dodecylsulfate (SDS), for the first time. Interplanar spacing (d001) and surface area of microporous zirconium phenylphosphonate are 1.47 nm and 198 m2g-1, respectively. FT-IR spectrum indicates absence or negligible amount of hydroxyls groups in zirconium phenylphosphonate sample, 31P solid MAS NMR also confirms the presence of trace amount of hydroxyl groups in zirconium phenylphosphonate. The presence of tetra-coordinated phosphorous ions and hexa-coordinated zirconium ions were realized by the 31P solid MAS NMR and UV-visible, respectively. Sulfonated derivative of zirconium phenylphosphonate, Zr(O3PC 6H4SO3H)19 (O3PC 6H5)0.1·3.7H2O were also prepared.",

keywords = "Layered, Mircroporous material, Sodium dodecylsulfate, Zirconium phenylphosphonate",

author = "Mal, {N. K.} and M. Sasidharan and M. Fujiwara and Y. Yamada and M. Matsukata",

year = "2004",

month = jan,

day = "1",

language = "English",

volume = "154 A",

pages = "1153--1159",

journal = "Studies in Surface Science and Catalysis",

issn = "0167-2991",

publisher = "Elsevier BV",

}

TY - JOUR

T1 - Synthesis and characterization of microporous layered zirconium phenylphosphonate

AU - Mal, N. K.

AU - Sasidharan, M.

AU - Fujiwara, M.

AU - Yamada, Y.

AU - Matsukata, M.

PY - 2004/1/1

Y1 - 2004/1/1

N2 - Microporous layered zirconium phenylphosphonate, Zr(O3P-C 6H5)2 was prepared in presence of sodium dodecylsulfate (SDS), for the first time. Interplanar spacing (d001) and surface area of microporous zirconium phenylphosphonate are 1.47 nm and 198 m2g-1, respectively. FT-IR spectrum indicates absence or negligible amount of hydroxyls groups in zirconium phenylphosphonate sample, 31P solid MAS NMR also confirms the presence of trace amount of hydroxyl groups in zirconium phenylphosphonate. The presence of tetra-coordinated phosphorous ions and hexa-coordinated zirconium ions were realized by the 31P solid MAS NMR and UV-visible, respectively. Sulfonated derivative of zirconium phenylphosphonate, Zr(O3PC 6H4SO3H)19 (O3PC 6H5)0.1·3.7H2O were also prepared.

AB - Microporous layered zirconium phenylphosphonate, Zr(O3P-C 6H5)2 was prepared in presence of sodium dodecylsulfate (SDS), for the first time. Interplanar spacing (d001) and surface area of microporous zirconium phenylphosphonate are 1.47 nm and 198 m2g-1, respectively. FT-IR spectrum indicates absence or negligible amount of hydroxyls groups in zirconium phenylphosphonate sample, 31P solid MAS NMR also confirms the presence of trace amount of hydroxyl groups in zirconium phenylphosphonate. The presence of tetra-coordinated phosphorous ions and hexa-coordinated zirconium ions were realized by the 31P solid MAS NMR and UV-visible, respectively. Sulfonated derivative of zirconium phenylphosphonate, Zr(O3PC 6H4SO3H)19 (O3PC 6H5)0.1·3.7H2O were also prepared.

KW - Layered

KW - Mircroporous material

KW - Sodium dodecylsulfate

KW - Zirconium phenylphosphonate

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M3 - Article

AN - SCOPUS:11844254398

SN - 0167-2991

VL - 154 A

SP - 1153

EP - 1159

JO - Studies in Surface Science and Catalysis

JF - Studies in Surface Science and Catalysis

ER -

Synthesis and characterization of microporous layered zirconium phenylphosphonate

Abstract

Keywords

ASJC Scopus subject areas

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