Synthesis and properties of novel sulfonated poly(phenylene ether)

Kenji Miyatake; Hua Zhou; Masahiro Watanabe

doi:10.1002/pola.20623

Synthesis and properties of novel sulfonated poly(phenylene ether)

Kenji Miyatake, Hua Zhou, Masahiro Watanabe^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

A Poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) based ionomer with pendant oxyethylene sulfonic acid was synthesized by the bromination of PPO. The bromination of PPO was carried out with NBS and benzoyl peroxide under irradiation with a 100-W flood lamp in CCl₄. Thermal analysis were performed on a Mac Science TG-DTA2000 equipped with a Bruker MS9600 mass spectrometer at a heating rate of 10°C/min under an argon atmosphere. The degree of bromination was found to be 0.22 Br per repeating unit by ₁H NMR analysis. The.

Original language	English
Pages (from-to)	1741-1744
Number of pages	4
Journal	Journal of Polymer Science, Part A: Polymer Chemistry
Volume	43
Issue number	8
DOIs	https://doi.org/10.1002/pola.20623
Publication status	Published - 2005 Apr 15
Externally published	Yes

Keywords

Conducting polymers
Fuel cells
Ionomers
Membranes
Poly(phenylene oxide)
Sulfonic acid groups

ASJC Scopus subject areas

Polymers and Plastics
Organic Chemistry
Materials Chemistry

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10.1002/pola.20623

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title = "Synthesis and properties of novel sulfonated poly(phenylene ether)",

abstract = "A Poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) based ionomer with pendant oxyethylene sulfonic acid was synthesized by the bromination of PPO. The bromination of PPO was carried out with NBS and benzoyl peroxide under irradiation with a 100-W flood lamp in CCl4. Thermal analysis were performed on a Mac Science TG-DTA2000 equipped with a Bruker MS9600 mass spectrometer at a heating rate of 10°C/min under an argon atmosphere. The degree of bromination was found to be 0.22 Br per repeating unit by 1H NMR analysis. The.",

keywords = "Conducting polymers, Fuel cells, Ionomers, Membranes, Poly(phenylene oxide), Sulfonic acid groups",

author = "Kenji Miyatake and Hua Zhou and Masahiro Watanabe",

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day = "15",

doi = "10.1002/pola.20623",

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volume = "43",

pages = "1741--1744",

journal = "Journal of Polymer Science, Part A: Polymer Chemistry",

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T1 - Synthesis and properties of novel sulfonated poly(phenylene ether)

AU - Miyatake, Kenji

AU - Zhou, Hua

AU - Watanabe, Masahiro

PY - 2005/4/15

Y1 - 2005/4/15

N2 - A Poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) based ionomer with pendant oxyethylene sulfonic acid was synthesized by the bromination of PPO. The bromination of PPO was carried out with NBS and benzoyl peroxide under irradiation with a 100-W flood lamp in CCl4. Thermal analysis were performed on a Mac Science TG-DTA2000 equipped with a Bruker MS9600 mass spectrometer at a heating rate of 10°C/min under an argon atmosphere. The degree of bromination was found to be 0.22 Br per repeating unit by 1H NMR analysis. The.

AB - A Poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) based ionomer with pendant oxyethylene sulfonic acid was synthesized by the bromination of PPO. The bromination of PPO was carried out with NBS and benzoyl peroxide under irradiation with a 100-W flood lamp in CCl4. Thermal analysis were performed on a Mac Science TG-DTA2000 equipped with a Bruker MS9600 mass spectrometer at a heating rate of 10°C/min under an argon atmosphere. The degree of bromination was found to be 0.22 Br per repeating unit by 1H NMR analysis. The.

KW - Conducting polymers

KW - Fuel cells

KW - Ionomers

KW - Membranes

KW - Poly(phenylene oxide)

KW - Sulfonic acid groups

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U2 - 10.1002/pola.20623

DO - 10.1002/pola.20623

M3 - Article

AN - SCOPUS:17644396655

SN - 0887-624X

VL - 43

SP - 1741

EP - 1744

JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

IS - 8

ER -

Synthesis and properties of novel sulfonated poly(phenylene ether)

Abstract

Keywords

ASJC Scopus subject areas

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